Activation of tellurium with zintl ions: {[Ge5TeI0]4- }, An inorganic polymer with germanium in three different oxidation states

Qichun Zhang, Gerasimos Armatas, Mercouri G. Kanatzidis

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Abstract

The solvothermal reaction among tellurium, manganese, and the Zintl compound K4Ge9 has led to the formation of a polymeric mlxed-valent complex {[Mn(en)3]2(Ge5Te 10)}n (1; en=ethylenediamine). The most interesting structural feature of this material Is the presence of three different oxidation states of germanium centers and the formation of Ge-Ge bonds In the infinite polymeric chains 1/∞{[Ge5Te10]4-). X-ray photoelectron spectroscopy characterization confirms the different oxidation states of germanium.

Original languageEnglish
Pages (from-to)8665-8667
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number18
DOIs
Publication statusPublished - Sep 21 2009

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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