Addition of Sn-OiPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy; Yuyang Wu; Mayfair C. Kung; Harold H Kung

doi:10.1021/acs.organomet.5b00973

Addition of Sn-OⁱPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy, Yuyang Wu, Mayfair C. Kung, Harold H Kung

Northwestern University

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by ¹H, ¹³C, and ¹¹⁹Sn NMR and ESI-MS.

Original language	English
Pages (from-to)	301-302
Number of pages	2
Journal	Organometallics
Volume	35
Issue number	3
DOIs	https://doi.org/10.1021/acs.organomet.5b00973
Publication status	Published - Feb 8 2016

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alkoxides

Alkenes

chelates

alkenes

insertion

Metals

Nuclear magnetic resonance

nuclear magnetic resonance

products

metals

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

Beletskiy, E. V., Wu, Y., Kung, M. C., & Kung, H. H. (2016). Addition of Sn-OⁱPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. Organometallics, 35(3), 301-302. https://doi.org/10.1021/acs.organomet.5b00973

Addition of Sn-OⁱPr across a C=C Bond : Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. / Beletskiy, Evgeny V.; Wu, Yuyang; Kung, Mayfair C.; Kung, Harold H.

In: Organometallics, Vol. 35, No. 3, 08.02.2016, p. 301-302.

Research output: Contribution to journal › Article

Beletskiy, EV, Wu, Y, Kung, MC & Kung, HH 2016, 'Addition of Sn-OⁱPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond', Organometallics, vol. 35, no. 3, pp. 301-302. https://doi.org/10.1021/acs.organomet.5b00973

Beletskiy EV, Wu Y, Kung MC, Kung HH. Addition of Sn-OⁱPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. Organometallics. 2016 Feb 8;35(3):301-302. https://doi.org/10.1021/acs.organomet.5b00973

Beletskiy, Evgeny V. ; Wu, Yuyang ; Kung, Mayfair C. ; Kung, Harold H. / Addition of Sn-OⁱPr across a C=C Bond : Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. In: Organometallics. 2016 ; Vol. 35, No. 3. pp. 301-302.

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Access to Document

10.1021/acs.organomet.5b00973