Addition of Sn-OiPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy, Yuyang Wu, Mayfair C. Kung, Harold H Kung

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5 Citations (Scopus)

Abstract

An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by 1H, 13C, and 119Sn NMR and ESI-MS.

Original languageEnglish
Pages (from-to)301-302
Number of pages2
JournalOrganometallics
Volume35
Issue number3
DOIs
Publication statusPublished - Feb 8 2016

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ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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