Addition of Sn-OiPr across a C=C Bond

Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy, Yuyang Wu, Mayfair C. Kung, Harold H Kung

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by 1H, 13C, and 119Sn NMR and ESI-MS.

Original languageEnglish
Pages (from-to)301-302
Number of pages2
JournalOrganometallics
Volume35
Issue number3
DOIs
Publication statusPublished - Feb 8 2016

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alkoxides
Alkenes
chelates
alkenes
insertion
Metals
Nuclear magnetic resonance
nuclear magnetic resonance
products
metals

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Addition of Sn-OiPr across a C=C Bond : Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. / Beletskiy, Evgeny V.; Wu, Yuyang; Kung, Mayfair C.; Kung, Harold H.

In: Organometallics, Vol. 35, No. 3, 08.02.2016, p. 301-302.

Research output: Contribution to journal › Article

Beletskiy, EV, Wu, Y, Kung, MC & Kung, HH 2016, 'Addition of Sn-OiPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond', Organometallics, vol. 35, no. 3, pp. 301-302. https://doi.org/10.1021/acs.organomet.5b00973
Beletskiy EV, Wu Y, Kung MC, Kung HH. Addition of Sn-OiPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. Organometallics. 2016 Feb 8;35(3):301-302. https://doi.org/10.1021/acs.organomet.5b00973
Beletskiy, Evgeny V. ; Wu, Yuyang ; Kung, Mayfair C. ; Kung, Harold H. / Addition of Sn-OiPr across a C=C Bond : Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond. In: Organometallics. 2016 ; Vol. 35, No. 3. pp. 301-302.
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