Addition of Sn-OiPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy; Yuyang Wu; Mayfair C. Kung; Harold H Kung

doi:10.1021/acs.organomet.5b00973

Addition of Sn-OⁱPr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Evgeny V. Beletskiy, Yuyang Wu, Mayfair C. Kung, Harold H Kung

Northwestern University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by ¹H, ¹³C, and ¹¹⁹Sn NMR and ESI-MS.

Original language	English
Pages (from-to)	301-302
Number of pages	2
Journal	Organometallics
Volume	35
Issue number	3
DOIs	https://doi.org/10.1021/acs.organomet.5b00973
Publication status	Published - Feb 8 2016

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by 1H, 13C, and 119Sn NMR and ESI-MS.",

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AB - An example of unusual addition of a main-group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by 1H, 13C, and 119Sn NMR and ESI-MS.

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