Aerobic epoxidation catalysed by transition metal substituted polyfluorooxometalates

Marco Bugnola, Ronny Neumann

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

First row transition metal substituted polyfluorooxmetalates with quasi Wells-Dawson structures and a nitro terminal ligand, [NaH2M(NO2)W17F6O55]q-, were used as catalysts for the aerobic epoxidation of cyclic alkenes. The Cu(NO2) analog combined the best traits of conversion and selectivity. Some C-C bond cleavage was also observed and cis isomers reacted preferentially without stereochemical inversion indicating an oxygen atom to double bond concerted reaction.

Original languageEnglish
Pages (from-to)14534-14537
Number of pages4
JournalDalton Transactions
Volume45
Issue number37
DOIs
Publication statusPublished - 2016

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Cycloparaffins
Epoxidation
Isomers
Transition metals
Oxygen
Ligands
Atoms
Catalysts

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Aerobic epoxidation catalysed by transition metal substituted polyfluorooxometalates. / Bugnola, Marco; Neumann, Ronny.

In: Dalton Transactions, Vol. 45, No. 37, 2016, p. 14534-14537.

Research output: Contribution to journalArticle

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