Abstract
We present structural and electrochemical analyses of a new double-wolframite compound: AgNa(VO2F2)2 or SSVOF. SSVOF is fully ordered and displays electrochemical characteristics that give insight into electrode design for energy storage beyond lithium-ion chemistries. The compound contains trioxovanadium fluoride octahedra that combine to form one-dimensional chain-like basic building units, characteristic of wolframite (NaWO4). The 1D chains are stacked to create 2D layers; the cations Ag+ and Na+ lie between these layers. The vanadium oxide-fluoride octahedra are ordered by the use of cations (Ag +, Na+) that differ in polarizability. In the case of sodium-ion batteries, thermodynamically, the use of a sodium anode introduces a 300 mV loss in overall cell voltage as compared to a lithium anode; however, this can be counter-balanced by introduction of fluoride into the framework to raise the reduction potentials via an inductive effect. This allows sodium-ion batteries to have comparable voltages to lithium systems. With SSVOF as a baseline compound, we have identified new materials design rules for emerging sodium-ion systems that do not apply to lithium-ion systems. These strategies can be applied broadly to provide materials of interest for fundamental structural chemistry and appreciable voltages for sodium-ion electrochemistry.
| Original language | English |
|---|---|
| Pages (from-to) | 9898-9906 |
| Number of pages | 9 |
| Journal | Journal of the American Chemical Society |
| Volume | 135 |
| Issue number | 26 |
| DOIs | |
| Publication status | Published - Jul 3 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
- Medicine(all)
Cite this
AgNa(VO2F2)2 : A trioxovanadium fluoride with unconventional electrochemical properties. / Donakowski, Martin D.; Görne, Arno; Vaughey, John T.; Poeppelmeier, Kenneth R.
In: Journal of the American Chemical Society, Vol. 135, No. 26, 03.07.2013, p. 9898-9906.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - AgNa(VO2F2)2
T2 - A trioxovanadium fluoride with unconventional electrochemical properties
AU - Donakowski, Martin D.
AU - Görne, Arno
AU - Vaughey, John T.
AU - Poeppelmeier, Kenneth R
PY - 2013/7/3
Y1 - 2013/7/3
N2 - We present structural and electrochemical analyses of a new double-wolframite compound: AgNa(VO2F2)2 or SSVOF. SSVOF is fully ordered and displays electrochemical characteristics that give insight into electrode design for energy storage beyond lithium-ion chemistries. The compound contains trioxovanadium fluoride octahedra that combine to form one-dimensional chain-like basic building units, characteristic of wolframite (NaWO4). The 1D chains are stacked to create 2D layers; the cations Ag+ and Na+ lie between these layers. The vanadium oxide-fluoride octahedra are ordered by the use of cations (Ag +, Na+) that differ in polarizability. In the case of sodium-ion batteries, thermodynamically, the use of a sodium anode introduces a 300 mV loss in overall cell voltage as compared to a lithium anode; however, this can be counter-balanced by introduction of fluoride into the framework to raise the reduction potentials via an inductive effect. This allows sodium-ion batteries to have comparable voltages to lithium systems. With SSVOF as a baseline compound, we have identified new materials design rules for emerging sodium-ion systems that do not apply to lithium-ion systems. These strategies can be applied broadly to provide materials of interest for fundamental structural chemistry and appreciable voltages for sodium-ion electrochemistry.
AB - We present structural and electrochemical analyses of a new double-wolframite compound: AgNa(VO2F2)2 or SSVOF. SSVOF is fully ordered and displays electrochemical characteristics that give insight into electrode design for energy storage beyond lithium-ion chemistries. The compound contains trioxovanadium fluoride octahedra that combine to form one-dimensional chain-like basic building units, characteristic of wolframite (NaWO4). The 1D chains are stacked to create 2D layers; the cations Ag+ and Na+ lie between these layers. The vanadium oxide-fluoride octahedra are ordered by the use of cations (Ag +, Na+) that differ in polarizability. In the case of sodium-ion batteries, thermodynamically, the use of a sodium anode introduces a 300 mV loss in overall cell voltage as compared to a lithium anode; however, this can be counter-balanced by introduction of fluoride into the framework to raise the reduction potentials via an inductive effect. This allows sodium-ion batteries to have comparable voltages to lithium systems. With SSVOF as a baseline compound, we have identified new materials design rules for emerging sodium-ion systems that do not apply to lithium-ion systems. These strategies can be applied broadly to provide materials of interest for fundamental structural chemistry and appreciable voltages for sodium-ion electrochemistry.
UR - http://www.scopus.com/inward/record.url?scp=84879771669&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84879771669&partnerID=8YFLogxK
U2 - 10.1021/ja404189t
DO - 10.1021/ja404189t
M3 - Article
C2 - 23796147
AN - SCOPUS:84879771669
VL - 135
SP - 9898
EP - 9906
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 26
ER -