Alcohol dehydration on monooxo W=O and Dioxo O=W=O Species

Zhenjun Li, Břetislav Šmíd, Yu Kwon Kim, Vladimír Matolín, Bruce D. Kay, Roger Rousseau, Zdenek Dohnálek

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15 Citations (Scopus)

Abstract

The dehydration of 1-propanol on nanoporous WO 3 films prepared via ballistic deposition at ∼20 K has been investigated using temperature-programmed desorption, infrared reflection absorption spectroscopy, and density functional theory. The as-deposited films are extremely efficient in 1-propanol dehydration to propene. This activity is correlated with the presence of dioxo O=W=O groups, whereas monooxo W=O species are shown to be inactive. Annealing of the films induces densification that results in the loss of catalytic activity due to the annihilation of O=W=O species.

Original languageEnglish
Pages (from-to)2168-2172
Number of pages5
JournalJournal of Physical Chemistry Letters
Volume3
Issue number16
DOIs
Publication statusPublished - Aug 16 2012

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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    Li, Z., Šmíd, B., Kim, Y. K., Matolín, V., Kay, B. D., Rousseau, R., & Dohnálek, Z. (2012). Alcohol dehydration on monooxo W=O and Dioxo O=W=O Species. Journal of Physical Chemistry Letters, 3(16), 2168-2172. https://doi.org/10.1021/jz300885v