Alkane dehydrogenation by C-H activation at iridium(III)

Kate E. Allen; D. Michael Heinekey; Alan S. Goldman; Karen I. Goldberg

doi:10.1021/om301267c

Alkane dehydrogenation by C-H activation at iridium(III)

Kate E. Allen, D. Michael Heinekey, Alan S. Goldman, Karen I. Goldberg

Rutgers University

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Stoichiometric alkane dehydrogenation utilizing an Ir^III pincer complex, (^dmPhebox)Ir(OAc)₂(OH₂) (1a), has been described. The reaction between 1a and octane resulted in quantitative formation of (^dmPhebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major product, indicative of terminal C-H activation by 1a. In contrast to prior reports of alkane dehydrogenation with Ir, C-H bond activation occurs at Ir^III and the dehydrogenation is not inhibited by nitrogen, olefin, or water.

Original language	English
Pages (from-to)	1579-1582
Number of pages	4
Journal	Organometallics
Volume	32
Issue number	6
DOIs	https://doi.org/10.1021/om301267c
Publication status	Published - Mar 25 2013

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "Stoichiometric alkane dehydrogenation utilizing an IrIII pincer complex, (dmPhebox)Ir(OAc)2(OH2) (1a), has been described. The reaction between 1a and octane resulted in quantitative formation of (dmPhebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major product, indicative of terminal C-H activation by 1a. In contrast to prior reports of alkane dehydrogenation with Ir, C-H bond activation occurs at IrIII and the dehydrogenation is not inhibited by nitrogen, olefin, or water.",

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T1 - Alkane dehydrogenation by C-H activation at iridium(III)

AU - Allen, Kate E.

AU - Heinekey, D. Michael

AU - Goldman, Alan S.

AU - Goldberg, Karen I.

PY - 2013/3/25

Y1 - 2013/3/25

N2 - Stoichiometric alkane dehydrogenation utilizing an IrIII pincer complex, (dmPhebox)Ir(OAc)2(OH2) (1a), has been described. The reaction between 1a and octane resulted in quantitative formation of (dmPhebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major product, indicative of terminal C-H activation by 1a. In contrast to prior reports of alkane dehydrogenation with Ir, C-H bond activation occurs at IrIII and the dehydrogenation is not inhibited by nitrogen, olefin, or water.

AB - Stoichiometric alkane dehydrogenation utilizing an IrIII pincer complex, (dmPhebox)Ir(OAc)2(OH2) (1a), has been described. The reaction between 1a and octane resulted in quantitative formation of (dmPhebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major product, indicative of terminal C-H activation by 1a. In contrast to prior reports of alkane dehydrogenation with Ir, C-H bond activation occurs at IrIII and the dehydrogenation is not inhibited by nitrogen, olefin, or water.

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