Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes

Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

Kuo Chen Shih, Alan S Goldman

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

Original languageEnglish
Pages (from-to)3390-3392
Number of pages3
JournalOrganometallics
Volume12
Issue number9
Publication statusPublished - 1993

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phosphine
Rhodium
Alkanes
Dehydrogenation
dehydrogenation
rhodium
phosphines
alkanes
Hydrogen
hydrogen

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes : Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step. / Shih, Kuo Chen; Goldman, Alan S.

In: Organometallics, Vol. 12, No. 9, 1993, p. 3390-3392.

Research output: Contribution to journal › Article

Shih, KC & Goldman, AS 1993, 'Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step', Organometallics, vol. 12, no. 9, pp. 3390-3392.
Shih KC, Goldman AS. Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step. Organometallics. 1993;12(9):3390-3392.
Shih, Kuo Chen ; Goldman, Alan S. / Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes : Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step. In: Organometallics. 1993 ; Vol. 12, No. 9. pp. 3390-3392.
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