Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

Kuo Chen Shih; Alan S Goldman

Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

Kuo Chen Shih, Alan S Goldman

Rutgers University

Research output: Contribution to journal › Article

26 Citations (Scopus)

Abstract

RhL₂Cl (L = PⁱPr₃) is found to dehydrogenate cyclooctane to give H₂RhL₂Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

Original language	English
Pages (from-to)	3390-3392
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	9
Publication status	Published - 1993

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

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Shih, K. C., & Goldman, A. S. (1993). Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step. Organometallics, 12(9), 3390-3392.

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title = "Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step",

abstract = "RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.",

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AB - RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

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