Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

Kuo Chen Shih; Alan S Goldman

Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

Kuo Chen Shih, Alan S Goldman

Rutgers University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

RhL₂Cl (L = PⁱPr₃) is found to dehydrogenate cyclooctane to give H₂RhL₂Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

Original language	English
Pages (from-to)	3390-3392
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	9
Publication status	Published - 1993

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

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title = "Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes: Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step",

abstract = "RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.",

author = "Shih, {Kuo Chen} and Goldman, {Alan S}",

year = "1993",

language = "English",

volume = "12",

pages = "3390--3392",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

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T1 - Alkane dehydrogenation catalyzed by rhodium(I) phosphine complexes

T2 - Observation of the stoichiometric alkane-to-rhodium hydrogen-transfer step

AU - Shih, Kuo Chen

AU - Goldman, Alan S

PY - 1993

Y1 - 1993

N2 - RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

AB - RhL2Cl (L = PiPr3) is found to dehydrogenate cyclooctane to give H2RhL2Cl and cyclooctene; this represents the first observation of the key hydrogen-transfer step proposed for related, catalytic alkane transfer-dehydrogenation systems. Using norbornene as a hydrogen acceptor, transfer-dehydrogenation is catalyzed but turnover numbers are low.

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M3 - Article

AN - SCOPUS:0001417675

VL - 12

SP - 3390

EP - 3392

JO - Organometallics

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