Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann, Alexander M. Khenkin

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

Original languageEnglish
Pages (from-to)1967-1968
Number of pages2
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - Sep 21 1998

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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