Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann; Alexander M. Khenkin

doi:10.1039/a804396e

Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann, Alexander M. Khenkin

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Manganese substituted polyoxometalates (POMs), such as Li₁₂[Mn^II₂ZnW(ZnW₉O ₃₄)₂] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

Original language	English
Pages (from-to)	1967-1968
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a804396e
Publication status	Published - Sep 21 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.",

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AB - Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

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