Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann, Alexander M. Khenkin

Research output: Contribution to journal › Article

34 Citations (Scopus)

Abstract

Manganese substituted polyoxometalates (POMs), such as Li12[MnII 2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

Original languageEnglish
Pages (from-to)1967-1968
Number of pages2
JournalChemical Communications
Issue number18
Publication statusPublished - Sep 21 1998

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Alkanes
Ozone
Manganese
Paraffins
Oxidation
Ketones
Paramagnetic resonance
Catalysts
1,2,4-trioxane

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species. / Neumann, Ronny; Khenkin, Alexander M.

In: Chemical Communications, No. 18, 21.09.1998, p. 1967-1968.

Research output: Contribution to journal › Article

Neumann, R & Khenkin, AM 1998, 'Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species', Chemical Communications, no. 18, pp. 1967-1968.
Neumann R, Khenkin AM. Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species. Chemical Communications. 1998 Sep 21;(18):1967-1968.
Neumann, Ronny ; Khenkin, Alexander M. / Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species. In: Chemical Communications. 1998 ; No. 18. pp. 1967-1968.
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