Alkene oxidation in water using hydrophobic silica particles derivatized with polyoxometalates as catalysts

Ronny Neumann, Hagit Miller

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium-polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.

Original languageEnglish
Pages (from-to)2277-2278
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
Publication statusPublished - 1995

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Silicates
Xerogels
Alkenes
Ammonium Compounds
Hydrogen peroxide
Silicon Dioxide
Organic solvents
Hydrogen Peroxide
Olefins
Silica
Ions
Oxidation
Catalysts
Water
polyoxometalate I

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "Alkene oxidation in water using hydrophobic silica particles derivatized with polyoxometalates as catalysts",
abstract = "An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium-polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30{\%} aqueous hydrogen peroxide in the absence of an organic solvent.",
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