Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

Joseph E. Sarneski; Demetrius Michos; H. Holden Thorp; Mary Didiuk; Thomas Poon; Jennifer Blewitt; Gary W Brudvig; Robert H. Crabtree

doi:10.1016/S0040-4039(00)92031-8

Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

Joseph E. Sarneski, Demetrius Michos, H. Holden Thorp, Mary Didiuk, Thomas Poon, Jennifer Blewitt, Gary W Brudvig, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article

52 Citations (Scopus)

Abstract

The system ROOH/[Mn₃O₄(dipy)₄(OH₂)₂](ClO₄)₄ hydroxylates alkanes and converts ArCRCH₂ to ArCRO with extremely high activity and good conversions and yields.

Original language	English
Pages (from-to)	1153-1156
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)92031-8
Publication status	Published - Feb 25 1991

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

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Sarneski, J. E., Michos, D., Holden Thorp, H., Didiuk, M., Poon, T., Blewitt, J., Brudvig, G. W., & Crabtree, R. H. (1991). Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. Tetrahedron Letters, 32(9), 1153-1156. https://doi.org/10.1016/S0040-4039(00)92031-8

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title = "Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.",

abstract = "The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.",

author = "Sarneski, {Joseph E.} and Demetrius Michos and {Holden Thorp}, H. and Mary Didiuk and Thomas Poon and Jennifer Blewitt and Brudvig, {Gary W} and Crabtree, {Robert H.}",

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AU - Sarneski, Joseph E.

AU - Michos, Demetrius

AU - Holden Thorp, H.

AU - Didiuk, Mary

AU - Poon, Thomas

AU - Blewitt, Jennifer

AU - Brudvig, Gary W

AU - Crabtree, Robert H.

PY - 1991/2/25

Y1 - 1991/2/25

N2 - The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.

AB - The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.

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