Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

Joseph E. Sarneski, Demetrius Michos, H. Holden Thorp, Mary Didiuk, Thomas Poon, Jennifer Blewitt, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.

Original languageEnglish
Pages (from-to)1153-1156
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number9
DOIs
Publication statusPublished - Feb 25 1991

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Fingerprint Dive into the research topics of 'Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.'. Together they form a unique fingerprint.

  • Cite this

    Sarneski, J. E., Michos, D., Holden Thorp, H., Didiuk, M., Poon, T., Blewitt, J., Brudvig, G. W., & Crabtree, R. H. (1991). Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. Tetrahedron Letters, 32(9), 1153-1156. https://doi.org/10.1016/S0040-4039(00)92031-8