Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

Joseph E. Sarneski, Demetrius Michos, H. Holden Thorp, Mary Didiuk, Thomas Poon, Jennifer Blewitt, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticlepeer-review

52 Citations (Scopus)

Abstract

The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.

Original languageEnglish
Pages (from-to)1153-1156
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number9
DOIs
Publication statusPublished - Feb 25 1991

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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