Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

Joseph E. Sarneski, Demetrius Michos, H. Holden Thorp, Mary Didiuk, Thomas Poon, Jennifer Blewitt, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCRCH2 to ArCRO with extremely high activity and good conversions and yields.

Original languageEnglish
Pages (from-to)1153-1156
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number9
DOIs
Publication statusPublished - Feb 25 1991

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Alkanes
Alkenes
Hydrogen Peroxide
Oxidation
Catalysts
perchlorate
manganese oxide

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Sarneski, J. E., Michos, D., Holden Thorp, H., Didiuk, M., Poon, T., Blewitt, J., ... Crabtree, R. H. (1991). Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. Tetrahedron Letters, 32(9), 1153-1156. https://doi.org/10.1016/S0040-4039(00)92031-8

Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. / Sarneski, Joseph E.; Michos, Demetrius; Holden Thorp, H.; Didiuk, Mary; Poon, Thomas; Blewitt, Jennifer; Brudvig, Gary W; Crabtree, Robert H.

In: Tetrahedron Letters, Vol. 32, No. 9, 25.02.1991, p. 1153-1156.

Research output: Contribution to journalArticle

Sarneski, JE, Michos, D, Holden Thorp, H, Didiuk, M, Poon, T, Blewitt, J, Brudvig, GW & Crabtree, RH 1991, 'Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.', Tetrahedron Letters, vol. 32, no. 9, pp. 1153-1156. https://doi.org/10.1016/S0040-4039(00)92031-8
Sarneski JE, Michos D, Holden Thorp H, Didiuk M, Poon T, Blewitt J et al. Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. Tetrahedron Letters. 1991 Feb 25;32(9):1153-1156. https://doi.org/10.1016/S0040-4039(00)92031-8
Sarneski, Joseph E. ; Michos, Demetrius ; Holden Thorp, H. ; Didiuk, Mary ; Poon, Thomas ; Blewitt, Jennifer ; Brudvig, Gary W ; Crabtree, Robert H. / Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. In: Tetrahedron Letters. 1991 ; Vol. 32, No. 9. pp. 1153-1156.
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