Amine/hydrido bifunctional nanoporous silica with small metal nanoparticles made onsite: Efficient dehydrogenation catalyst

Yang Zhu, Takahiro Nakanishi, Kazuyoshi Kanamori, Kazuki Nakanishi, Shun Ichii, Kohji Iwaida, Yu Masui, Toshiyuki Kamei, Toyoshi Shimada, Akihito Kumamoto, Yumi H. Ikuhara, Mina Jeon, George Hasegawa, Teddy Asefa, Masamoto Tafu, Chang Won Yoon

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Multifunctional catalysts are of great interest in catalysis because their multiple types of catalytic or functional groups can cooperatively promote catalytic transformations better than their constituents do individually. Herein we report a new synthetic route involving the surface functionalization of nanoporous silica with a rationally designed and synthesized dihydrosilane (3-aminopropylmethylsilane) that leads to the introduction of catalytically active grafted organoamine as well as single metal atoms and ultrasmall Pd or Ag-doped Pd nanoparticles via on-site reduction of metal ions. The resulting nanomaterials serve as highly effective bifunctional dehydrogenative catalysts for generation of H2 from formic acid.

Original languageEnglish
Pages (from-to)36-41
Number of pages6
JournalACS Applied Materials and Interfaces
Volume9
Issue number1
DOIs
Publication statusPublished - 2017

Fingerprint

formic acid
Metal nanoparticles
Dehydrogenation
Silicon Dioxide
Amines
Silica
Catalysts
Formic acid
Nanostructured materials
Functional groups
Catalysis
Metal ions
Metals
Nanoparticles
Atoms

Keywords

  • Amino/hydrido bifunctional
  • Bifunctional catalyst
  • Dehydrogenation catalyst
  • Formic acid dehydrogenation
  • Metal nanoparticles
  • Nanoporous silica
  • Onsite synthesis
  • Supported nanoparticles

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Amine/hydrido bifunctional nanoporous silica with small metal nanoparticles made onsite : Efficient dehydrogenation catalyst. / Zhu, Yang; Nakanishi, Takahiro; Kanamori, Kazuyoshi; Nakanishi, Kazuki; Ichii, Shun; Iwaida, Kohji; Masui, Yu; Kamei, Toshiyuki; Shimada, Toyoshi; Kumamoto, Akihito; Ikuhara, Yumi H.; Jeon, Mina; Hasegawa, George; Asefa, Teddy; Tafu, Masamoto; Yoon, Chang Won.

In: ACS Applied Materials and Interfaces, Vol. 9, No. 1, 2017, p. 36-41.

Research output: Contribution to journalArticle

Zhu, Y, Nakanishi, T, Kanamori, K, Nakanishi, K, Ichii, S, Iwaida, K, Masui, Y, Kamei, T, Shimada, T, Kumamoto, A, Ikuhara, YH, Jeon, M, Hasegawa, G, Asefa, T, Tafu, M & Yoon, CW 2017, 'Amine/hydrido bifunctional nanoporous silica with small metal nanoparticles made onsite: Efficient dehydrogenation catalyst', ACS Applied Materials and Interfaces, vol. 9, no. 1, pp. 36-41. https://doi.org/10.1021/acsami.6b12972
Zhu, Yang ; Nakanishi, Takahiro ; Kanamori, Kazuyoshi ; Nakanishi, Kazuki ; Ichii, Shun ; Iwaida, Kohji ; Masui, Yu ; Kamei, Toshiyuki ; Shimada, Toyoshi ; Kumamoto, Akihito ; Ikuhara, Yumi H. ; Jeon, Mina ; Hasegawa, George ; Asefa, Teddy ; Tafu, Masamoto ; Yoon, Chang Won. / Amine/hydrido bifunctional nanoporous silica with small metal nanoparticles made onsite : Efficient dehydrogenation catalyst. In: ACS Applied Materials and Interfaces. 2017 ; Vol. 9, No. 1. pp. 36-41.
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