Amorphous piezo- and pyroelectric phases of BaZrO3 and SrTiO3

David Ehre, Vera Lyahovitskaya, Alexander Tagantsev, Igor Lubomirsky

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Amorphous piezo and pyroelectric phases of BaZr3 and SrTiO 3 can form quasiamorphous phases although neither of them have a polar crystalline polymorph. Amorphous films of SrTiO3 or BaZrO 3 (50- 200 nm thick) were deposited by radiofrequency magnetron sputtering on highly conductive Si substrates. The as-deposited amorphous films were then pulled through a temperature gradient in order to induce a strong inhomogeneous stress that could align the local bonding units. Stoichiometry of all samples was verified with X-ray photoelectron spectroscopy before and after heat treatment. These findings are the first instance of successful manipulation of local bonding units to obtain a noncrystalline inorganic solid with desired properties. Though qualitative, this method is highly reliable because the influences of electrical interferences, friction-induced electricity, and electrostriction can easily be excluded.

Original languageEnglish
Pages (from-to)1515-1517
Number of pages3
JournalAdvanced Materials
Volume19
Issue number11
DOIs
Publication statusPublished - Jun 4 2007

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Amorphous films
Electrostriction
Crystallization
Polymorphism
Stoichiometry
Magnetron sputtering
Thermal gradients
Electricity
X ray photoelectron spectroscopy
Heat treatment
Friction
Crystalline materials
Substrates
strontium titanium oxide

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Amorphous piezo- and pyroelectric phases of BaZrO3 and SrTiO3 . / Ehre, David; Lyahovitskaya, Vera; Tagantsev, Alexander; Lubomirsky, Igor.

In: Advanced Materials, Vol. 19, No. 11, 04.06.2007, p. 1515-1517.

Research output: Contribution to journalArticle

Ehre, David ; Lyahovitskaya, Vera ; Tagantsev, Alexander ; Lubomirsky, Igor. / Amorphous piezo- and pyroelectric phases of BaZrO3 and SrTiO3 . In: Advanced Materials. 2007 ; Vol. 19, No. 11. pp. 1515-1517.
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