Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

Yanfeng Wang, Yanli Chen, Renjie Li, Shuangqing Wang, Wei Su, Pan Ma, Michael R Wasielewski, Xiyou Li, Jianzhuang Jiang

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective π - π interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir - Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm2 V-1 s-1 and current modulation of 103. This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the π - A isotherms and UV - vis absorption.

Original languageEnglish
Pages (from-to)5836-5842
Number of pages7
JournalLangmuir
Volume23
Issue number10
DOIs
Publication statusPublished - May 8 2007

Fingerprint

Perylene
Organic field effect transistors
Field effect transistors
Dimers
field effect transistors
dimers
Derivatives
Langmuir Blodgett films
rings
Carrier mobility
Langmuir-Blodgett films
carrier mobility
Isotherms
isotherms
Modulation
interactions
modulation
configurations

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Wang, Y., Chen, Y., Li, R., Wang, S., Su, W., Ma, P., ... Jiang, J. (2007). Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor. Langmuir, 23(10), 5836-5842. https://doi.org/10.1021/la063729f

Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor. / Wang, Yanfeng; Chen, Yanli; Li, Renjie; Wang, Shuangqing; Su, Wei; Ma, Pan; Wasielewski, Michael R; Li, Xiyou; Jiang, Jianzhuang.

In: Langmuir, Vol. 23, No. 10, 08.05.2007, p. 5836-5842.

Research output: Contribution to journalArticle

Wang, Y, Chen, Y, Li, R, Wang, S, Su, W, Ma, P, Wasielewski, MR, Li, X & Jiang, J 2007, 'Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor', Langmuir, vol. 23, no. 10, pp. 5836-5842. https://doi.org/10.1021/la063729f
Wang, Yanfeng ; Chen, Yanli ; Li, Renjie ; Wang, Shuangqing ; Su, Wei ; Ma, Pan ; Wasielewski, Michael R ; Li, Xiyou ; Jiang, Jianzhuang. / Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor. In: Langmuir. 2007 ; Vol. 23, No. 10. pp. 5836-5842.
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