An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

Dong I. Yoon, Suzanne Bélanger, Joseph T Hupp, Charlotte L. Stern

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The crystal structure of the adduct dibenzo-42-crown-14 (OC-6-22)-tetraammine( 1,10-phenanthroline-N,N′)-ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, [Ru(C12H8N2)(NH3) 4](PF6)2.C36H56O 14.CH2-Cl2, is reported. The guest Ru complex is located deep within the U-shaped cavity formed by folding of the flexible crown host. The ammine ligands of the Ru complex participate in an extensive network of hydrogen bonds with the ether O atoms of the crown. Weak π stacking appears to occur between the aromatic rings of the phenanthroline ligand and the benzene groups of the crown ether.

Original languageEnglish
Pages (from-to)1427-1431
Number of pages5
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number10
Publication statusPublished - Oct 15 1998

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Ruthenium
Crowns
ruthenium
adducts
ethers
ammines
Ligands
Crown Ethers
ligands
Phenanthrolines
Methylene Chloride
Benzene
Ether
folding
Hydrogen
Hydrogen bonds
Crystal structure
benzene
hydrogen bonds
Atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14. / Yoon, Dong I.; Bélanger, Suzanne; Hupp, Joseph T; Stern, Charlotte L.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 10, 15.10.1998, p. 1427-1431.

Research output: Contribution to journalArticle

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