An adiabatic model of chemisorbed molecules

electron spectroscopy and excited-state potential-energy surfaces

D. R. Jennison, Ellen Stechel, A. R. Burns

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We review models that have been used to understand excited states of chemisorbed species, focussing on CO and NO, and encounter problems in attempting to fit all observables. We then introduce a new model. We show that a purely-electronic adiabatic approximation leads to an accurate solution for the system wavefunction in the limit that the molecule-substrate interaction is weak. This produces a configuration-interaction theory that has a Hubbard-like form. We derive semi-empirical parameters for the NO:Pt(111) system and find that the transfer integral for the 2π-substrate interaction is small for all choices of the screened electron-electron interaction, U. This suggests, for this system, that the substrate indeed adiabatically follows the fluctuations in adsorbate charge which are inherent in a covalent bond. We propose that our model is robust and applies to many adsorbed molecules. We then investigate low-lying excited-states of the metal-molecule bond.

Original languageEnglish
Pages (from-to)9-18
Number of pages10
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume72
Issue numberC
DOIs
Publication statusPublished - Mar 31 1995

Fingerprint

Potential energy surfaces
Electron spectroscopy
Excited states
electron spectroscopy
potential energy
Molecules
Substrates
excitation
Electron-electron interactions
molecules
Covalent bonds
covalent bonds
Adsorbates
Carbon Monoxide
Wave functions
encounters
configuration interaction
electron scattering
Metals
approximation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Radiation

Cite this

An adiabatic model of chemisorbed molecules : electron spectroscopy and excited-state potential-energy surfaces. / Jennison, D. R.; Stechel, Ellen; Burns, A. R.

In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 72, No. C, 31.03.1995, p. 9-18.

Research output: Contribution to journalArticle

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