An evaluation of the rotational barrier about the BN bond of 1-aminoborepins

Arthur J. Ashe, Wolfram Klein, Roger Rousseau

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14 Citations (Scopus)

Abstract

13C NMR spectroscopy has been used to determined the barriers to rotation about the BN bonds of 1-(N-benzyl-N-methylamino)borepin and 1-(N-benzyl-N-methylamino)-4,5-dihydroborepin as 18 and 19.8 kcal mol-1, respectively. The corresponding rotational barriers of a variety of aminoboranes have been calculated using the semi-empirical AM1 method.

Original languageEnglish
Pages (from-to)21-23
Number of pages3
JournalJournal of Organometallic Chemistry
Volume468
Issue number1-2
DOIs
Publication statusPublished - Apr 5 1994

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Keywords

  • AM1 calculations
  • Aminoborane
  • Borepin
  • Boron
  • Nitrogen
  • Nuclear magnetic resonance

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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