Abstract
A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
Original language | English |
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Pages (from-to) | 276-281 |
Number of pages | 6 |
Journal | Chemistry - A European Journal |
Volume | 16 |
Issue number | 1 |
DOIs | |
Publication status | Published - Jan 4 2010 |
Keywords
- Adsorption
- CO
- Dynamic structures
- Gated sorption
- Hysteresis
- Metal-organic frameworks
- Porous materials
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry