An interpenetrated framework material with hysteretic CO2 uptake

Karen L. Mulfort; Omar K. Farha; Christos D. Malliakas; Mercouri G. Kanatzidis; Joseph T. Hupp

doi:10.1002/chem.200902104

An interpenetrated framework material with hysteretic CO₂ uptake

Karen L. Mulfort, Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis, Joseph T. Hupp

Northwestern University

Research output: Contribution to journal › Article › peer-review

176 Citations (Scopus)

Abstract

A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO₂. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO₂ sorption most likely involve the interpenetrated frameworks moving with respect to each other.

Original language	English
Pages (from-to)	276-281
Number of pages	6
Journal	Chemistry - A European Journal
Volume	16
Issue number	1
DOIs	https://doi.org/10.1002/chem.200902104
Publication status	Published - Jan 4 2010

Keywords

Adsorption
CO
Dynamic structures
Gated sorption
Hysteresis
Metal-organic frameworks
Porous materials

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.200902104

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