An interpenetrated framework material with hysteretic CO2 uptake

Karen L. Mulfort; Omar K. Farha; Christos D. Malliakas; Mercouri G Kanatzidis; Joseph T Hupp

doi:10.1002/chem.200902104

An interpenetrated framework material with hysteretic CO₂ uptake

Karen L. Mulfort, Omar K. Farha, Christos D. Malliakas, Mercouri G Kanatzidis, Joseph T Hupp

Northwestern University

Research output: Contribution to journal › Article

169 Citations (Scopus)

Abstract

A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO₂. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO₂ sorption most likely involve the interpenetrated frameworks moving with respect to each other.

Original language	English
Pages (from-to)	276-281
Number of pages	6
Journal	Chemistry - A European Journal
Volume	16
Issue number	1
DOIs	https://doi.org/10.1002/chem.200902104
Publication status	Published - Jan 4 2010

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Keywords

Adsorption
CO
Dynamic structures
Gated sorption
Hysteresis
Metal-organic frameworks
Porous materials

ASJC Scopus subject areas

Chemistry(all)

Cite this

Mulfort, K. L., Farha, O. K., Malliakas, C. D., Kanatzidis, M. G., & Hupp, J. T. (2010). An interpenetrated framework material with hysteretic CO₂ uptake. Chemistry - A European Journal, 16(1), 276-281. https://doi.org/10.1002/chem.200902104

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Access to Document

10.1002/chem.200902104