Abstract
A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
| Original language | English |
|---|---|
| Pages (from-to) | 276-281 |
| Number of pages | 6 |
| Journal | Chemistry - A European Journal |
| Volume | 16 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 4 2010 |
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Keywords
- Adsorption
- CO
- Dynamic structures
- Gated sorption
- Hysteresis
- Metal-organic frameworks
- Porous materials
ASJC Scopus subject areas
- Chemistry(all)
Cite this
An interpenetrated framework material with hysteretic CO2 uptake. / Mulfort, Karen L.; Farha, Omar K.; Malliakas, Christos D.; Kanatzidis, Mercouri G; Hupp, Joseph T.
In: Chemistry - A European Journal, Vol. 16, No. 1, 04.01.2010, p. 276-281.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An interpenetrated framework material with hysteretic CO2 uptake
AU - Mulfort, Karen L.
AU - Farha, Omar K.
AU - Malliakas, Christos D.
AU - Kanatzidis, Mercouri G
AU - Hupp, Joseph T
PY - 2010/1/4
Y1 - 2010/1/4
N2 - A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
AB - A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
KW - Adsorption
KW - CO
KW - Dynamic structures
KW - Gated sorption
KW - Hysteresis
KW - Metal-organic frameworks
KW - Porous materials
UR - http://www.scopus.com/inward/record.url?scp=73949153861&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=73949153861&partnerID=8YFLogxK
U2 - 10.1002/chem.200902104
DO - 10.1002/chem.200902104
M3 - Article
C2 - 19918820
AN - SCOPUS:73949153861
VL - 16
SP - 276
EP - 281
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 1
ER -