Abstract
A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
| Original language | English |
|---|---|
| Pages (from-to) | 276-281 |
| Number of pages | 6 |
| Journal | Chemistry - A European Journal |
| Volume | 16 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 4 2010 |
Keywords
- Adsorption
- CO
- Dynamic structures
- Gated sorption
- Hysteresis
- Metal-organic frameworks
- Porous materials
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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Cite this
Mulfort, K. L., Farha, O. K., Malliakas, C. D., Kanatzidis, M. G., & Hupp, J. T. (2010). An interpenetrated framework material with hysteretic CO2 uptake. Chemistry - A European Journal, 16(1), 276-281. https://doi.org/10.1002/chem.200902104