Abstract
The interaction of potassium with carbon monoxide and benzene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. We find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface.
| Original language | English |
|---|---|
| Pages (from-to) | 3207-3211 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry |
| Volume | 89 |
| Issue number | 15 |
| Publication status | Published - 1985 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
An ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface. / Kudo, M.; Garfunkel, Eric; Somorjai, G. A.
In: Journal of Physical Chemistry, Vol. 89, No. 15, 1985, p. 3207-3211.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface
AU - Kudo, M.
AU - Garfunkel, Eric
AU - Somorjai, G. A.
PY - 1985
Y1 - 1985
N2 - The interaction of potassium with carbon monoxide and benzene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. We find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface.
AB - The interaction of potassium with carbon monoxide and benzene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. We find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface.
UR - http://www.scopus.com/inward/record.url?scp=0008903983&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0008903983&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0008903983
VL - 89
SP - 3207
EP - 3211
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
SN - 0022-3654
IS - 15
ER -