An uncommon bonding mode of a familiar ligand: A molybdenum complex with a four-electron donor chelating η3-PPh3 ligand, and its structural determination using synchrotron radiation

Tan Yun Cheng, David J. Szalda, R Morris Bullock

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Abstract

A crystallographic study using synchrotron radiation shows that a C=C bond of one phenyl group of a PPh3 ligand bonds to Mo in [Cp(CO)2(PPh3)Mo]+, resulting in an unusual bonding mode in which PPh3 functions as a chelating four-electron donor ligand.

Original languageEnglish
Pages (from-to)1629-1630
Number of pages2
JournalChemical Communications
Issue number17
Publication statusPublished - Sep 7 1999

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Molybdenum
Chelation
Synchrotron radiation
Ligands
Electrons
Carbon Monoxide

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "A crystallographic study using synchrotron radiation shows that a C=C bond of one phenyl group of a PPh3 ligand bonds to Mo in [Cp(CO)2(PPh3)Mo]+, resulting in an unusual bonding mode in which PPh3 functions as a chelating four-electron donor ligand.",
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