Analysis of isomerization in compounds displaying restricted rotation of aryl groups

John Devens Gust; Kurt Mislow

Analysis of isomerization in compounds displaying restricted rotation of aryl groups

John Devens Gust, Kurt Mislow

Arizona State University

Research output: Contribution to journal › Article › peer-review

239 Citations (Scopus)

Abstract

A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar₃ZX (e.g., Ar₃CH, Ar₃P) and Ar₃Z (e.g., Ar₃B), and also for the diaryl systems Ar₂ZXY (e.g., Ar₂CHCl, Ar₂PH), Ar₂ZX₂ (e.g., Ar₂CH₂, Ar₂O), and Ar₂ZX (e.g., Ar₂CO, Ar₂O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

Original language	English
Pages (from-to)	1535-1547
Number of pages	13
Journal	Journal of the American Chemical Society
Volume	95
Issue number	5
Publication status	Published - 1973

ASJC Scopus subject areas

Chemistry(all)

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title = "Analysis of isomerization in compounds displaying restricted rotation of aryl groups",

abstract = "A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.",

author = "Gust, {John Devens} and Kurt Mislow",

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T1 - Analysis of isomerization in compounds displaying restricted rotation of aryl groups

AU - Gust, John Devens

AU - Mislow, Kurt

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N2 - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

AB - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

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