Analysis of isomerization in compounds displaying restricted rotation of aryl groups

John Devens Gust, Kurt Mislow

Research output: Contribution to journalArticle

230 Citations (Scopus)

Abstract

A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

Original languageEnglish
Pages (from-to)1535-1547
Number of pages13
JournalJournal of the American Chemical Society
Volume95
Issue number5
Publication statusPublished - 1973

Fingerprint

Isomerization
Ligands
Isomerism
Molecular Structure
Molecular structure

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Analysis of isomerization in compounds displaying restricted rotation of aryl groups. / Gust, John Devens; Mislow, Kurt.

In: Journal of the American Chemical Society, Vol. 95, No. 5, 1973, p. 1535-1547.

Research output: Contribution to journalArticle

@article{034d45069dc9401792dacc4adf7585eb,
title = "Analysis of isomerization in compounds displaying restricted rotation of aryl groups",
abstract = "A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.",
author = "Gust, {John Devens} and Kurt Mislow",
year = "1973",
language = "English",
volume = "95",
pages = "1535--1547",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "5",

}

TY - JOUR

T1 - Analysis of isomerization in compounds displaying restricted rotation of aryl groups

AU - Gust, John Devens

AU - Mislow, Kurt

PY - 1973

Y1 - 1973

N2 - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

AB - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.

UR - http://www.scopus.com/inward/record.url?scp=33947087968&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33947087968&partnerID=8YFLogxK

M3 - Article

VL - 95

SP - 1535

EP - 1547

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 5

ER -