Abstract
A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.
| Original language | English |
|---|---|
| Pages (from-to) | 1535-1547 |
| Number of pages | 13 |
| Journal | Journal of the American Chemical Society |
| Volume | 95 |
| Issue number | 5 |
| Publication status | Published - 1973 |
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Analysis of isomerization in compounds displaying restricted rotation of aryl groups. / Gust, John Devens; Mislow, Kurt.
In: Journal of the American Chemical Society, Vol. 95, No. 5, 1973, p. 1535-1547.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Analysis of isomerization in compounds displaying restricted rotation of aryl groups
AU - Gust, John Devens
AU - Mislow, Kurt
PY - 1973
Y1 - 1973
N2 - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.
AB - A general and systematic approach to the topological analysis of isomerism and isomerization has been developed for compounds belonging to the triaryl systems Ar3ZX (e.g., Ar3CH, Ar3P) and Ar3Z (e.g., Ar3B), and also for the diaryl systems Ar2ZXY (e.g., Ar2CHCl, Ar2PH), Ar2ZX2 (e.g., Ar2CH2, Ar2O), and Ar2ZX (e.g., Ar2CO, Ar2O), where X and Y represent ligands or pseudo-ligands. The results may be displayed in the form of graphs, as illustrated by application to several examples from the literature. This method of analysis is broadly applicable to a large variety of molecular structures.
UR - http://www.scopus.com/inward/record.url?scp=33947087968&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33947087968&partnerID=8YFLogxK
M3 - Article
VL - 95
SP - 1535
EP - 1547
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 5
ER -