Analysis of molecular square size and purity via pulsed-field gradient NMR spectroscopy

William H. Otto, Melinda H. Keefe, Kathryn E. Splan, Joseph T. Hupp, Cynthia K. Larive

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Abstract

The size (volume) of a large tetrametallic molecular square, that has resisted characterization by mass spectrometry, has been determined by pulsed-field gradient NMR spectroscopy, a technique that reports on self-diffusion coefficients. These scale inversely with hydrodynamic radii, which in turn scale approximately as the cube of the assembly's mass. The technique has also been used to determine whether NMR spectral complexities observed for the new compound are due to contamination with chemically related assemblies, or instead reflect the intrinsic structural complexities of the compound itself.

Original languageEnglish
Pages (from-to)6172-6174
Number of pages3
JournalInorganic Chemistry
Volume41
Issue number24
DOIs
Publication statusPublished - Dec 2 2002

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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