Anodes for Lithium-Ion Batteries Based on Type i Silicon Clathrate Ba8Al16Si30 - Role of Processing on Surface Properties and Electrochemical Behavior

Ran Zhao, Svilen Bobev, Lakshmi Krishna, Ting Yang, J. Mark Weller, Hangkun Jing, Candace Chan

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Type I silicon clathrates based on Ba8AlySi46-y (8 < y < 12) have been studied as potential anodes for lithium-ion batteries and display electrochemical properties that are distinct from those found in conventional silicon anodes. Processing steps such as ball-milling (typically used to reduce the particle size) and acid/base treatment (used to remove nonclathrate impurities) may modify the clathrate surface structure or introduce defects, which could affect the observed electrochemical properties. In this work, we perform a systematic investigation of Ba8AlySi46-y clathrates with y ≈ 16, i.e, having a composition near Ba8Al16Si30, which perfectly satisfies the Zintl condition. The roles of ball-milling and acid/base treatment were investigated using electrochemical, X-ray diffraction, electron microscopy, X-ray photoelectron and Raman spectroscopy analysis. The results showed that acid/base treatment removed impurities from the synthesis, but also led to formation of a surface oxide layer that inhibited lithiation. Ball-milling could remove the surface oxide and result in the formation of an amorphous surface layer, with the observed charge storage capacity correlated with the thickness of this amorphous layer. According to the XRD and electrochemical analysis, all lithiation/delithiation processes are proposed to occur in single phase reactions at the surface with no discernible changes to the crystal structure in the bulk. Electrochemical impedance spectroscopy results suggest that the mechanism of lithiation is through surface-dominated, Faradaic processes. This suggests that for off-stoichiometric clathrates, as we studied in our previous work, Li+ insertion at defects or vacancies on the framework may be the origin of reversible Li cycling. However, for clathrates Ba8AlySi46-y with y ≈ 16, Li insertion in the structure is unfavorable and low capacities are observed unless amorphous surface layers are introduced by ball-milling.

Original languageEnglish
Pages (from-to)41246-41257
Number of pages12
JournalACS Applied Materials and Interfaces
Volume9
Issue number47
DOIs
Publication statusPublished - Nov 29 2017

Keywords

  • anode
  • clathrate
  • Lithium-ion batteries
  • silicon
  • surface properties

ASJC Scopus subject areas

  • Materials Science(all)

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