Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework

V. Krungleviciute, K. Lask, L. Heroux, A. D. Migone, J. Y. Lee, Jing Li, A. Skoulidas

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.

Original languageEnglish
Pages (from-to)3106-3109
Number of pages4
JournalLangmuir
Volume23
Issue number6
DOIs
Publication statusPublished - Mar 13 2007

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Argon
Benzene
Metals
benzene
argon
Adsorption
adsorption
metals
Experiments
Adsorption isotherms
isotherms
simulation
heat
Temperature
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Krungleviciute, V., Lask, K., Heroux, L., Migone, A. D., Lee, J. Y., Li, J., & Skoulidas, A. (2007). Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework. Langmuir, 23(6), 3106-3109. https://doi.org/10.1021/la061871a

Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework. / Krungleviciute, V.; Lask, K.; Heroux, L.; Migone, A. D.; Lee, J. Y.; Li, Jing; Skoulidas, A.

In: Langmuir, Vol. 23, No. 6, 13.03.2007, p. 3106-3109.

Research output: Contribution to journalArticle

Krungleviciute, V, Lask, K, Heroux, L, Migone, AD, Lee, JY, Li, J & Skoulidas, A 2007, 'Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework', Langmuir, vol. 23, no. 6, pp. 3106-3109. https://doi.org/10.1021/la061871a
Krungleviciute V, Lask K, Heroux L, Migone AD, Lee JY, Li J et al. Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework. Langmuir. 2007 Mar 13;23(6):3106-3109. https://doi.org/10.1021/la061871a
Krungleviciute, V. ; Lask, K. ; Heroux, L. ; Migone, A. D. ; Lee, J. Y. ; Li, Jing ; Skoulidas, A. / Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework. In: Langmuir. 2007 ; Vol. 23, No. 6. pp. 3106-3109.
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