Assessing surface permeabilities from transient guest profiles in nanoporous host materials

Despina Tzoulaki, Lars Heinke, Hyuna Lim, Jing Li, David Olson, Jürgen Caro, Rajamani Krishna, Christian Chmelik, Jörg Karger

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.

Original languageEnglish
Pages (from-to)3525-3528
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number19
DOIs
Publication statusPublished - Apr 27 2009

Fingerprint

Crystals
Alkanes
Chain length
Organic compounds
Paraffins
Microscopic examination
Mass transfer
Metals
Imaging techniques
Molecules

Keywords

  • Coordination polymers
  • Nanoporous materials
  • Surface permeability
  • Surface resistance

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Assessing surface permeabilities from transient guest profiles in nanoporous host materials. / Tzoulaki, Despina; Heinke, Lars; Lim, Hyuna; Li, Jing; Olson, David; Caro, Jürgen; Krishna, Rajamani; Chmelik, Christian; Karger, Jörg.

In: Angewandte Chemie - International Edition, Vol. 48, No. 19, 27.04.2009, p. 3525-3528.

Research output: Contribution to journalArticle

Tzoulaki, D, Heinke, L, Lim, H, Li, J, Olson, D, Caro, J, Krishna, R, Chmelik, C & Karger, J 2009, 'Assessing surface permeabilities from transient guest profiles in nanoporous host materials', Angewandte Chemie - International Edition, vol. 48, no. 19, pp. 3525-3528. https://doi.org/10.1002/anie.200804785
Tzoulaki, Despina ; Heinke, Lars ; Lim, Hyuna ; Li, Jing ; Olson, David ; Caro, Jürgen ; Krishna, Rajamani ; Chmelik, Christian ; Karger, Jörg. / Assessing surface permeabilities from transient guest profiles in nanoporous host materials. In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 19. pp. 3525-3528.
@article{4b3564c32ab34e10a948cc7dd4201800,
title = "Assessing surface permeabilities from transient guest profiles in nanoporous host materials",
abstract = "Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.",
keywords = "Coordination polymers, Nanoporous materials, Surface permeability, Surface resistance",
author = "Despina Tzoulaki and Lars Heinke and Hyuna Lim and Jing Li and David Olson and J{\"u}rgen Caro and Rajamani Krishna and Christian Chmelik and J{\"o}rg Karger",
year = "2009",
month = "4",
day = "27",
doi = "10.1002/anie.200804785",
language = "English",
volume = "48",
pages = "3525--3528",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "19",

}

TY - JOUR

T1 - Assessing surface permeabilities from transient guest profiles in nanoporous host materials

AU - Tzoulaki, Despina

AU - Heinke, Lars

AU - Lim, Hyuna

AU - Li, Jing

AU - Olson, David

AU - Caro, Jürgen

AU - Krishna, Rajamani

AU - Chmelik, Christian

AU - Karger, Jörg

PY - 2009/4/27

Y1 - 2009/4/27

N2 - Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.

AB - Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.

KW - Coordination polymers

KW - Nanoporous materials

KW - Surface permeability

KW - Surface resistance

UR - http://www.scopus.com/inward/record.url?scp=70349786170&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70349786170&partnerID=8YFLogxK

U2 - 10.1002/anie.200804785

DO - 10.1002/anie.200804785

M3 - Article

VL - 48

SP - 3525

EP - 3528

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 19

ER -