Abstract
Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.
| Original language | English |
|---|---|
| Pages (from-to) | 3525-3528 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 48 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - Apr 27 2009 |
Keywords
- Coordination polymers
- Nanoporous materials
- Surface permeability
- Surface resistance
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Tzoulaki, D., Heinke, L., Lim, H., Li, J., Olson, D., Caro, J., Krishna, R., Chmelik, C., & Karger, J. (2009). Assessing surface permeabilities from transient guest profiles in nanoporous host materials. Angewandte Chemie - International Edition, 48(19), 3525-3528. https://doi.org/10.1002/anie.200804785