Auto-reconvolution

a new method of data retrieval from time-resolved emission anisotropy measurements

Andrew J. Marsh, Gary Rumbles, Ian Soutar, Linda Swanson

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A new method, that of "auto-reconvolution", for the recovery of rotational relaxation data from time-resolved anisotropy measurements (TRAMS) is reported. In this approach the observed time-dependent "parallel" component of luminescence intensity, I|(t), is used to deconvolute its orthogonal counterpart, I(t). The procedure has been validated in TRAMS experiments upon four fluorescently labelled polymers in dilute solution, following vertically polarized excitation using synchrotron radiation. In each case, excellent agreement with data retrieved by the impulse reconvolution method was achieved.

Original languageEnglish
Pages (from-to)31-36
Number of pages6
JournalChemical Physics Letters
Volume195
Issue number1
DOIs
Publication statusPublished - Jul 10 1992

Fingerprint

data retrieval
Anisotropy
anisotropy
Synchrotron radiation
Luminescence
Polymers
Recovery
impulses
synchrotron radiation
recovery
luminescence
Experiments
polymers
excitation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Auto-reconvolution : a new method of data retrieval from time-resolved emission anisotropy measurements. / Marsh, Andrew J.; Rumbles, Gary; Soutar, Ian; Swanson, Linda.

In: Chemical Physics Letters, Vol. 195, No. 1, 10.07.1992, p. 31-36.

Research output: Contribution to journalArticle

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