BaCIBF4: A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf

Min Zhang, Shilie Pan, Zhihua Yang, Ying Wang, Xin Su, Yun Yang, Zhenjun Huang, Shujuan Han, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

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Abstract

A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.

Original languageEnglish
Pages (from-to)4740-4745
Number of pages6
JournalJournal of Materials Chemistry C
Volume1
Issue number31
DOIs
Publication statusPublished - Aug 21 2013

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Laser damage
Transparency
Alkaline Earth Metals
Alkaline earth metals
Borates
Crystals
Harmonic generation
Electronic structure
Energy dispersive spectroscopy
Crystal structure
Direction compound

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

BaCIBF4 : A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf. / Zhang, Min; Pan, Shilie; Yang, Zhihua; Wang, Ying; Su, Xin; Yang, Yun; Huang, Zhenjun; Han, Shujuan; Poeppelmeier, Kenneth R.

In: Journal of Materials Chemistry C, Vol. 1, No. 31, 21.08.2013, p. 4740-4745.

Research output: Contribution to journalArticle

Zhang, Min ; Pan, Shilie ; Yang, Zhihua ; Wang, Ying ; Su, Xin ; Yang, Yun ; Huang, Zhenjun ; Han, Shujuan ; Poeppelmeier, Kenneth R. / BaCIBF4 : A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf. In: Journal of Materials Chemistry C. 2013 ; Vol. 1, No. 31. pp. 4740-4745.
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