Abstract
A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.
| Original language | English |
|---|---|
| Pages (from-to) | 4740-4745 |
| Number of pages | 6 |
| Journal | Journal of Materials Chemistry C |
| Volume | 1 |
| Issue number | 31 |
| DOIs | |
| Publication status | Published - Aug 21 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Chemistry
Cite this
BaCIBF4 : A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf. / Zhang, Min; Pan, Shilie; Yang, Zhihua; Wang, Ying; Su, Xin; Yang, Yun; Huang, Zhenjun; Han, Shujuan; Poeppelmeier, Kenneth R.
In: Journal of Materials Chemistry C, Vol. 1, No. 31, 21.08.2013, p. 4740-4745.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - BaCIBF4
T2 - A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf
AU - Zhang, Min
AU - Pan, Shilie
AU - Yang, Zhihua
AU - Wang, Ying
AU - Su, Xin
AU - Yang, Yun
AU - Huang, Zhenjun
AU - Han, Shujuan
AU - Poeppelmeier, Kenneth R
PY - 2013/8/21
Y1 - 2013/8/21
N2 - A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.
AB - A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.
UR - http://www.scopus.com/inward/record.url?scp=84900402231&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84900402231&partnerID=8YFLogxK
U2 - 10.1039/c3tc30581c
DO - 10.1039/c3tc30581c
M3 - Article
AN - SCOPUS:84900402231
VL - 1
SP - 4740
EP - 4745
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
SN - 2050-7526
IS - 31
ER -