TY - JOUR
T1 - BaCIBF4
T2 - A new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage thresholdf
AU - Zhang, Min
AU - Pan, Shilie
AU - Yang, Zhihua
AU - Wang, Ying
AU - Su, Xin
AU - Yang, Yun
AU - Huang, Zhenjun
AU - Han, Shujuan
AU - Poeppelmeier, Kenneth R.
PY - 2013/8/21
Y1 - 2013/8/21
N2 - A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.
AB - A new noncentrosymmetric alkaline earth metal ha I id e borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2CI2]2+ layers with anionic [BF4]- layers along the b direction, and the [Ba2CI2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 |im, and the laser damage threshold of the crystal is about 6.8 GW cm-2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.
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U2 - 10.1039/c3tc30581c
DO - 10.1039/c3tc30581c
M3 - Article
AN - SCOPUS:84900402231
VL - 1
SP - 4740
EP - 4745
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
SN - 2050-7526
IS - 31
ER -