Benzodithiophene Hole-Transporting Materials for Efficient Tin-Based Perovskite Solar Cells

Sureshraju Vegiraju, Weijun Ke, Pragya Priyanka, Jen Shyang Ni, Yi Ching Wu, Ioannis Spanopoulos, Shueh Lin Yau, Tobin J Marks, Ming Chou Chen, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

Abstract

Developing efficient interfacial hole transporting materials (HTMs) is crucial for achieving high-performance Pb-free Sn-based halide perovskite solar cells (PSCs). Here, a new series of benzodithiophene (BDT)-based organic small molecules containing tetra- and di-triphenyl amine donors prepared via a straightforward and scalable synthetic route is reported. The thermal, optical, and electrochemical properties of two BDT-based molecules are shown to be structurally and energetically suitable to serve as HTMs for Sn-based PSCs. It is reported here that ethylenediammonium/formamidinium tin iodide solar cells using BDT-based HTMs deliver a champion power conversion efficiency up to 7.59%, outperforming analogous reference solar cells using traditional and expensive HTMs. Thus, these BDT-based molecules are promising candidates as HTMs for the fabrication of high-performance Sn-based PSCs.

Original languageEnglish
Article number1905393
JournalAdvanced Functional Materials
DOIs
Publication statusAccepted/In press - Jan 1 2019

    Fingerprint

Keywords

  • benzodithiophene
  • lead-free
  • perovskite solar cells
  • tin
  • triphenylamine

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Vegiraju, S., Ke, W., Priyanka, P., Ni, J. S., Wu, Y. C., Spanopoulos, I., Yau, S. L., Marks, T. J., Chen, M. C., & Kanatzidis, M. G. (Accepted/In press). Benzodithiophene Hole-Transporting Materials for Efficient Tin-Based Perovskite Solar Cells. Advanced Functional Materials, [1905393]. https://doi.org/10.1002/adfm.201905393