Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization

Liting Li; Matthew V. Metz; Tobin J Marks; Louise Liable-Sands; Arnold L. Rheingold

Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization

Liting Li, Matthew V. Metz, Tobin J Marks, Louise Liable-Sands, Arnold L. Rheingold

Northwestern University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

5 Citations (Scopus)

Abstract

In this study, the binuclear constrained geometry catalyst (CGC) (3,3′-μ-CH₂CH₂) {n⁵-indenyl) [1-SiMe₂(^tBuN)] (ZrMe₂)}₂ [EBI(CGCZrMe₂)₂ (Zr₂) and trityl bisborate (Ph₃(C⁺)₂[1,4-(C₆F₅)₃BC₆F₄ B(C₆F₅)₃]^2-(B₂) were synthesized and characterized to serve as new types of binuclear single-site Ziegler-Natta catalysts and cocatalysts for olefin polymerization. The monometallic metallocene complex (3-CH₂CH₃-indenyl) [1-SiMe₂(^tBuN)]ZrMe₂ (Zr₁) was synthesized as a control for studies of cooperativity in ethylene polymerization. Polymerization studies show that these catalysts and cocatalysts are highly active in mediating ethylene polymerization.

Original language	English
Title of host publication	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Publisher	ACS
Pages	1912-1913
Number of pages	2
Volume	41
Edition	2
Publication status	Published - Aug 2000
Event	Washington,DC. Meeting - Washington, DC, USA Duration: Aug 20 2000 → Aug 24 2000

Other

Other	Washington,DC. Meeting
City	Washington, DC, USA
Period	8/20/00 → 8/24/00

ASJC Scopus subject areas

Polymers and Plastics

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Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. / Li, Liting; Metz, Matthew V.; Marks, Tobin J; Liable-Sands, Louise; Rheingold, Arnold L.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 2. ed. ACS, 2000. p. 1912-1913.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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title = "Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization",

abstract = "In this study, the binuclear constrained geometry catalyst (CGC) (3,3′-μ-CH2CH2) {n5-indenyl) [1-SiMe2(tBuN)] (ZrMe2)}2 [EBI(CGCZrMe2)2 (Zr2) and trityl bisborate (Ph3(C+)2[1,4-(C6F5)3BC6F4 B(C6F5)3]2-(B2) were synthesized and characterized to serve as new types of binuclear single-site Ziegler-Natta catalysts and cocatalysts for olefin polymerization. The monometallic metallocene complex (3-CH2CH3-indenyl) [1-SiMe2(tBuN)]ZrMe2 (Zr1) was synthesized as a control for studies of cooperativity in ethylene polymerization. Polymerization studies show that these catalysts and cocatalysts are highly active in mediating ethylene polymerization.",

author = "Liting Li and Metz, {Matthew V.} and Marks, {Tobin J} and Louise Liable-Sands and Rheingold, {Arnold L.}",

year = "2000",

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language = "English",

volume = "41",

pages = "1912--1913",

booktitle = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

publisher = "ACS",

edition = "2",

note = "Washington,DC. Meeting ; Conference date: 20-08-2000 Through 24-08-2000",

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TY - GEN

T1 - Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization

AU - Li, Liting

AU - Metz, Matthew V.

AU - Marks, Tobin J

AU - Liable-Sands, Louise

AU - Rheingold, Arnold L.

PY - 2000/8

Y1 - 2000/8

N2 - In this study, the binuclear constrained geometry catalyst (CGC) (3,3′-μ-CH2CH2) {n5-indenyl) [1-SiMe2(tBuN)] (ZrMe2)}2 [EBI(CGCZrMe2)2 (Zr2) and trityl bisborate (Ph3(C+)2[1,4-(C6F5)3BC6F4 B(C6F5)3]2-(B2) were synthesized and characterized to serve as new types of binuclear single-site Ziegler-Natta catalysts and cocatalysts for olefin polymerization. The monometallic metallocene complex (3-CH2CH3-indenyl) [1-SiMe2(tBuN)]ZrMe2 (Zr1) was synthesized as a control for studies of cooperativity in ethylene polymerization. Polymerization studies show that these catalysts and cocatalysts are highly active in mediating ethylene polymerization.

AB - In this study, the binuclear constrained geometry catalyst (CGC) (3,3′-μ-CH2CH2) {n5-indenyl) [1-SiMe2(tBuN)] (ZrMe2)}2 [EBI(CGCZrMe2)2 (Zr2) and trityl bisborate (Ph3(C+)2[1,4-(C6F5)3BC6F4 B(C6F5)3]2-(B2) were synthesized and characterized to serve as new types of binuclear single-site Ziegler-Natta catalysts and cocatalysts for olefin polymerization. The monometallic metallocene complex (3-CH2CH3-indenyl) [1-SiMe2(tBuN)]ZrMe2 (Zr1) was synthesized as a control for studies of cooperativity in ethylene polymerization. Polymerization studies show that these catalysts and cocatalysts are highly active in mediating ethylene polymerization.

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M3 - Conference contribution

AN - SCOPUS:0034250147

VL - 41

SP - 1912

EP - 1913

BT - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

PB - ACS

T2 - Washington,DC. Meeting

Y2 - 20 August 2000 through 24 August 2000

ER -

Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization

Abstract

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ASJC Scopus subject areas

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