Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization

Liting Li, Matthew V. Metz, Tobin J Marks, Louise Liable-Sands, Arnold L. Rheingold

Research output: Chapter in Book/Report/Conference proceedingConference contribution

5 Citations (Scopus)

Abstract

In this study, the binuclear constrained geometry catalyst (CGC) (3,3′-μ-CH2CH2) {n5-indenyl) [1-SiMe2(tBuN)] (ZrMe2)}2 [EBI(CGCZrMe2)2 (Zr2) and trityl bisborate (Ph3(C+)2[1,4-(C6F5)3BC6F4 B(C6F5)3]2-(B2) were synthesized and characterized to serve as new types of binuclear single-site Ziegler-Natta catalysts and cocatalysts for olefin polymerization. The monometallic metallocene complex (3-CH2CH3-indenyl) [1-SiMe2(tBuN)]ZrMe2 (Zr1) was synthesized as a control for studies of cooperativity in ethylene polymerization. Polymerization studies show that these catalysts and cocatalysts are highly active in mediating ethylene polymerization.

Original languageEnglish
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages1912-1913
Number of pages2
Volume41
Edition2
Publication statusPublished - Aug 2000
EventWashington,DC. Meeting - Washington, DC, USA
Duration: Aug 20 2000Aug 24 2000

Other

OtherWashington,DC. Meeting
CityWashington, DC, USA
Period8/20/008/24/00

Fingerprint

Alkenes
Olefins
Polymerization
Catalysts
Geometry
Ethylene
ethylene

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Li, L., Metz, M. V., Marks, T. J., Liable-Sands, L., & Rheingold, A. L. (2000). Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 41, pp. 1912-1913). ACS.

Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. / Li, Liting; Metz, Matthew V.; Marks, Tobin J; Liable-Sands, Louise; Rheingold, Arnold L.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 2. ed. ACS, 2000. p. 1912-1913.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Li, L, Metz, MV, Marks, TJ, Liable-Sands, L & Rheingold, AL 2000, Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 41, ACS, pp. 1912-1913, Washington,DC. Meeting, Washington, DC, USA, 8/20/00.
Li L, Metz MV, Marks TJ, Liable-Sands L, Rheingold AL. Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 41. ACS. 2000. p. 1912-1913
Li, Liting ; Metz, Matthew V. ; Marks, Tobin J ; Liable-Sands, Louise ; Rheingold, Arnold L. / Binuclear constrained geometry catalysts and binuclear bisborate cocatalysts for olefin polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 2. ed. ACS, 2000. pp. 1912-1913
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