{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

Scott A. Heston; Bruce C. Noll; Monte L. Helm

doi:10.1107/S1600536809022405

{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ³ P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

Scott A. Heston, Bruce C. Noll, Monte L. Helm

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

In the title compound, [PtCl(C₃₄H₃₃P ₃)]PF₆, the Pt^II cation adopts a distorted square-planar PtClP₃ geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF₆^- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

Original language	English
Pages (from-to)	m793
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	7
DOIs	https://doi.org/10.1107/S1600536809022405
Publication status	Published - Jul 27 2009

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ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Heston, S. A., Noll, B. C., & Helm, M. L. (2009). {Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ³ P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate. Acta Crystallographica Section E: Structure Reports Online, 65(7), m793. https://doi.org/10.1107/S1600536809022405

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abstract = "In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.",

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AB - In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

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Access to Document

10.1107/S1600536809022405