{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

Scott A. Heston, Bruce C. Noll, Monte Helm

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number7
DOIs
Publication statusPublished - 2009

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phosphine
phosphines
Anions
Cations
Chlorides
Negative ions
Positive ions
chlorides
Ligands
Ions
anions
cations
Atoms
ligands
Geometry
geometry
atoms
ions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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abstract = "In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.",
author = "Heston, {Scott A.} and Noll, {Bruce C.} and Monte Helm",
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publisher = "International Union of Crystallography",
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T1 - {Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

AU - Heston, Scott A.

AU - Noll, Bruce C.

AU - Helm, Monte

PY - 2009

Y1 - 2009

N2 - In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

AB - In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

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JO - Acta Crystallographica Section E: Structure Reports Online

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