{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

Scott A. Heston; Bruce C. Noll; Monte L. Helm

doi:10.1107/S1600536809022405

{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ³ P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

Scott A. Heston, Bruce C. Noll, Monte L. Helm

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [PtCl(C₃₄H₃₃P ₃)]PF₆, the Pt^II cation adopts a distorted square-planar PtClP₃ geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF₆^- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

Original language	English
Pages (from-to)	m793
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	7
DOIs	https://doi.org/10.1107/S1600536809022405
Publication status	Published - 2009

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536809022405

Fingerprint Dive into the research topics of '{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ<sup>3</sup> P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate'. Together they form a unique fingerprint.

Cite this

@article{27ece298946349b5813c4285b1d95d11,

title = "{Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate",

abstract = "In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.",

author = "Heston, {Scott A.} and Noll, {Bruce C.} and Helm, {Monte L.}",

year = "2009",

doi = "10.1107/S1600536809022405",

language = "English",

volume = "65",

pages = "m793",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - {Bis[2-(diphenylphosphino)ethyl]phenyl-phosphine-κ3 P,P′,P″}chloridoplatinium(II) hexa-fluoridophosphate

AU - Heston, Scott A.

AU - Noll, Bruce C.

AU - Helm, Monte L.

PY - 2009

Y1 - 2009

N2 - In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

AB - In the title compound, [PtCl(C34H33P 3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′, P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6- anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.

UR - http://www.scopus.com/inward/record.url?scp=67650838663&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67650838663&partnerID=8YFLogxK

U2 - 10.1107/S1600536809022405

DO - 10.1107/S1600536809022405

M3 - Article

C2 - 21582720

AN - SCOPUS:67650838663

VL - 65

SP - m793

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 7

ER -