Bond activation and catalysis by ruthenium pincer complexes

Chidambaram Gunanathan, David Milstein

Research output: Contribution to journalReview article

489 Citations (Scopus)

Abstract

Activation of inert chemical bonds by transition metal complexes is an area of utmost importance. Efficient bond activation can provide a leading entry to successful catalytic design with the potential of providing greener synthetic methods for useful products. These coordinatively saturated and unsaturated ruthenium pincer complexes with heteroaromatic and aliphatic backbones developed in recent years exhibit new reactivities, activate strong chemical bonds, and act as efficient catalysts for several synthetic methods including unprecedented green transformations, the pivotal interest of this Review. One of the characteristic properties of pincer complexes is the ability to stabilize low valent metal complexes with uncommon geometries.

Original languageEnglish
Pages (from-to)12024-12087
Number of pages64
JournalChemical reviews
Volume114
Issue number24
DOIs
Publication statusPublished - Dec 24 2014

ASJC Scopus subject areas

  • Chemistry(all)

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