Borophene as a prototype for synthetic 2D materials development

Andrew J. Mannix, Zhuhua Zhang, Nathan P. Guisinger, Boris I. Yakobson, Mark C Hersam

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

The synthesis of 2D materials with no analogous bulk layered allotropes promises a substantial breadth of physical and chemical properties through the diverse structural options afforded by substrate-dependent epitaxy. However, despite the joint theoretical and experimental efforts to guide materials discovery, successful demonstrations of synthetic 2D materials have been rare. The recent synthesis of 2D boron polymorphs (that is, borophene) provides a notable example of such success. In this Perspective, we discuss recent progress and future opportunities for borophene research. Borophene combines unique mechanical properties with anisotropic metallicity, which complements the canon of conventional 2D materials. The multi-centre characteristics of boron-boron bonding lead to the formation of configurationally varied, vacancy-mediated structural motifs, providing unprecedented diversity in a mono-elemental 2D system with potential for electronic applications, chemical functionalization, materials synthesis and complex heterostructures. With its foundations in computationally guided synthesis, borophene can serve as a prototype for ongoing efforts to discover and exploit synthetic 2D materials.

Original languageEnglish
Pages (from-to)444-450
Number of pages7
JournalNature Nanotechnology
Volume13
Issue number6
DOIs
Publication statusPublished - Jun 1 2018

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prototypes
boron
Boron
synthesis
chemical properties
complement
epitaxy
metallicity
physical properties
mechanical properties
Polymorphism
Epitaxial growth
Chemical properties
Vacancies
Heterojunctions
Demonstrations
Physical properties
electronics
Mechanical properties
Substrates

ASJC Scopus subject areas

  • Bioengineering
  • Atomic and Molecular Physics, and Optics
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

Cite this

Borophene as a prototype for synthetic 2D materials development. / Mannix, Andrew J.; Zhang, Zhuhua; Guisinger, Nathan P.; Yakobson, Boris I.; Hersam, Mark C.

In: Nature Nanotechnology, Vol. 13, No. 6, 01.06.2018, p. 444-450.

Research output: Contribution to journalArticle

Mannix, Andrew J. ; Zhang, Zhuhua ; Guisinger, Nathan P. ; Yakobson, Boris I. ; Hersam, Mark C. / Borophene as a prototype for synthetic 2D materials development. In: Nature Nanotechnology. 2018 ; Vol. 13, No. 6. pp. 444-450.
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