Borophene-graphene heterostructures

Xiaolong Liu, Mark C. Hersam

Research output: Contribution to journalArticle

Abstract

Integration of dissimilar two-dimensional (2D) materials is essential for nanoelectronic applications. Compared to vertical stacking, covalent lateral stitching requires bottom-up synthesis, resulting in rare realizations of 2D lateral heterostructures. Because of its polymorphism and diverse bonding geometries, borophene is a promising candidate for 2D heterostructures, although suitable synthesis conditions have not yet been demonstrated. Here, we report lateral and vertical integration of borophene with graphene. Topographic and spatially resolved spectroscopic measurements reveal nearly atomically sharp lateral interfaces despite imperfect crystallographic lattice and symmetry matching. In addition, boron intercalation under graphene results in rotationally commensurate vertical heterostructures. The rich bonding configurations of boron suggest that borophene can be integrated into a diverse range of 2D heterostructures.

Original languageEnglish
Article numbereaax6444
JournalScience Advances
Volume5
Issue number10
DOIs
Publication statusPublished - Oct 11 2019

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graphene
boron
polymorphism
synthesis
intercalation
symmetry
geometry
configurations

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)
  • General

Cite this

Borophene-graphene heterostructures. / Liu, Xiaolong; Hersam, Mark C.

In: Science Advances, Vol. 5, No. 10, eaax6444, 11.10.2019.

Research output: Contribution to journalArticle

Liu, Xiaolong ; Hersam, Mark C. / Borophene-graphene heterostructures. In: Science Advances. 2019 ; Vol. 5, No. 10.
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