Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene

Manny Hillman; Linda Matyevich; Etsuko Fujita; Uttam Jagwani; Jefferson McGowan

doi:10.1021/om00069a022

Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene

Manny Hillman, Linda Matyevich, Etsuko Fujita, Uttam Jagwani, Jefferson McGowan

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Dilithiation of a trimethylene-bridged ferrocene with n-butyllithium and TMEDA selectively metalated the ring at the 2,2′- or the 3,3′-positions. The dilithio derivatives were converted to the dicarboxylic acid, the dibromo, and the diiodo derivatives.

Original language	English
Pages (from-to)	1226-1229
Number of pages	4
Journal	Organometallics
Volume	1
Issue number	9
DOIs	https://doi.org/10.1021/om00069a022
Publication status	Published - Jan 1 1982

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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