Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene

Manny Hillman; Linda Matyevich; Etsuko Fujita; Uttam Jagwani; Jefferson McGowan

doi:10.1021/om00069a022

Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene

Manny Hillman, Linda Matyevich, Etsuko Fujita, Uttam Jagwani, Jefferson McGowan

Brookhaven National Laboratory

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

Dilithiation of a trimethylene-bridged ferrocene with n-butyllithium and TMEDA selectively metalated the ring at the 2,2′- or the 3,3′-positions. The dilithio derivatives were converted to the dicarboxylic acid, the dibromo, and the diiodo derivatives.

Original language	English
Pages (from-to)	1226-1229
Number of pages	4
Journal	Organometallics
Volume	1
Issue number	9
DOIs	https://doi.org/10.1021/om00069a022
Publication status	Published - Jan 1 1982

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Hillman, M., Matyevich, L., Fujita, E., Jagwani, U., & McGowan, J. (1982). Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene. Organometallics, 1(9), 1226-1229. https://doi.org/10.1021/om00069a022

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Access to Document

10.1021/om00069a022