Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene

Manny Hillman, Linda Matyevich, Etsuko Fujita, Uttam Jagwani, Jefferson McGowan

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Dilithiation of a trimethylene-bridged ferrocene with n-butyllithium and TMEDA selectively metalated the ring at the 2,2′- or the 3,3′-positions. The dilithio derivatives were converted to the dicarboxylic acid, the dibromo, and the diiodo derivatives.

Original languageEnglish
Pages (from-to)1226-1229
Number of pages4
JournalOrganometallics
Volume1
Issue number9
DOIs
Publication statusPublished - Jan 1 1982

Fingerprint

ferrocenes
dicarboxylic acids
Derivatives
Dicarboxylic Acids
rings
ferrocene
n-butyllithium
cyclopropane
phenyllithium

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene. / Hillman, Manny; Matyevich, Linda; Fujita, Etsuko; Jagwani, Uttam; McGowan, Jefferson.

In: Organometallics, Vol. 1, No. 9, 01.01.1982, p. 1226-1229.

Research output: Contribution to journalArticle

Hillman, Manny ; Matyevich, Linda ; Fujita, Etsuko ; Jagwani, Uttam ; McGowan, Jefferson. / Bridged Ferrocenes. 9. Lithiation and Subsequent Reactions of 1,1′-Trimethyleneferrocene. In: Organometallics. 1982 ; Vol. 1, No. 9. pp. 1226-1229.
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