Abstract
The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 105-114 |
| Number of pages | 10 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 218 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Sep 22 1981 |
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ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry
Cite this
Bridged Ferrocenes VIII. Correlation of redox potentials with structure. / Fujita, Etsuko; Gordon, Barry; Hillman, Manny; Nagy, Agnes G.
In: Journal of Organometallic Chemistry, Vol. 218, No. 1, 22.09.1981, p. 105-114.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Bridged Ferrocenes VIII. Correlation of redox potentials with structure
AU - Fujita, Etsuko
AU - Gordon, Barry
AU - Hillman, Manny
AU - Nagy, Agnes G.
PY - 1981/9/22
Y1 - 1981/9/22
N2 - The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.
AB - The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0038648134&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0038648134&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)80991-2
DO - 10.1016/S0022-328X(00)80991-2
M3 - Article
AN - SCOPUS:0038648134
VL - 218
SP - 105
EP - 114
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -