TY - JOUR
T1 - Bridged Ferrocenes VIII. Correlation of redox potentials with structure
AU - Fujita, Etsuko
AU - Gordon, Barry
AU - Hillman, Manny
AU - Nagy, Agnes G.
N1 - Funding Information:
We are indebted to Drs. John J. Eisch, T.E. Bitterwolf and P. Sherman for valuable discussions. This work was supported by the Division of Chemical Sciences, U.S. Department of Energy, Washington, D.C., under contract No. DE-AC02-76CH00016.
PY - 1981/9/22
Y1 - 1981/9/22
N2 - The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.
AB - The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.
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U2 - 10.1016/S0022-328X(00)80991-2
DO - 10.1016/S0022-328X(00)80991-2
M3 - Article
AN - SCOPUS:0038648134
VL - 218
SP - 105
EP - 114
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -