Bridged Ferrocenes VIII. Correlation of redox potentials with structure

Etsuko Fujita, Barry Gordon, Manny Hillman, Agnes G. Nagy

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.

Original languageEnglish
Pages (from-to)105-114
Number of pages10
JournalJournal of Organometallic Chemistry
Volume218
Issue number1
DOIs
Publication statusPublished - Sep 22 1981

Fingerprint

ferrocenes
Hydrocarbons
Oxidation-Reduction
Iron
Oxidation
rings
hydrocarbons
alignment
iron
oxidation

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Bridged Ferrocenes VIII. Correlation of redox potentials with structure. / Fujita, Etsuko; Gordon, Barry; Hillman, Manny; Nagy, Agnes G.

In: Journal of Organometallic Chemistry, Vol. 218, No. 1, 22.09.1981, p. 105-114.

Research output: Contribution to journalArticle

Fujita, Etsuko ; Gordon, Barry ; Hillman, Manny ; Nagy, Agnes G. / Bridged Ferrocenes VIII. Correlation of redox potentials with structure. In: Journal of Organometallic Chemistry. 1981 ; Vol. 218, No. 1. pp. 105-114.
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