Bridged Ferrocenes VIII. Correlation of redox potentials with structure

Etsuko Fujita; Barry Gordon; Manny Hillman; Agnes G. Nagy

doi:10.1016/S0022-328X(00)80991-2

Bridged Ferrocenes VIII. Correlation of redox potentials with structure

Etsuko Fujita, Barry Gordon, Manny Hillman, Agnes G. Nagy

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The redox potentials for oxidation of ferrocenes with hydrocarbon bridges and of corresponding ketoferrocenes were measured. For the reduced compound correlations were observed between the potentials and the iron to ring distances. For the ketoferrocenes, the importance of proper alignment of the carbonyl with the cyclopentadienyl rings is noted. Other possible relationships are discussed.

Original language	English
Pages (from-to)	105-114
Number of pages	10
Journal	Journal of Organometallic Chemistry
Volume	218
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)80991-2
Publication status	Published - Sep 22 1981

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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