Bright-state expansion and optimal control of highly excited polyatomics

Matjaž Kaluža, James T. Muckerman

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A basis expansion of a quantum state of a molecule in a small orthogonal set of dynamically motivated, active bright states is presented and tested. The active bright states are derived from wavepackets (in a discrete variable representation) corresponding to different times in the time evolution of the molecule in a specified external laser field. Time evolution using the active bright-state representation is computationally less intensive and contains the essential dynamics in the quasiharmonic, quasicontinuum, and continuum regimes. Knowledge of the exact molecular spectroscopy is not needed. The active bright-state representation is thus well suited for optimal-control calculations which require a large number of wavepacket propagations.

Original languageEnglish
Pages (from-to)161-167
Number of pages7
JournalChemical Physics Letters
Volume239
Issue number1-3
DOIs
Publication statusPublished - Jun 9 1995

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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