Broad band optical characterization of sol-gel TiO2 thin film microstructure evolution with temperature

Sarika Phadke, Judith D. Sorge, Sherwood Hachtmann, Dunbar P Birnie

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Titanium dioxide (TiO2) thin films have been produced by spin coating a titanium isopropoxide sol on silicon wafer substrates. The structural evolution of the thin films in terms of decomposition, crystallization and densification has been monitored as a function of annealing temperature from 100 to 700 °C using optical characterization and other techniques. The effect of annealing temperature on the refractive index and extinction coefficient of these TiO2 thin films was studied in the range of 0.62 to 4.96 eV photon energy (250-2000 nm wavelength) using spectroscopic ellipsometry. Thermal gravimetric analysis and atomic force microscopy support the ellipsometry data and provide information about structural transformations in the titania thin films with respect to different annealing temperatures. These data help construct a coherent picture of the decomposition of the sol-gel precursors and the creation of dense layers of TiO2. It was observed that the refractive index increased from 2.02 to 2.45 at 2.48 eV (500 nm) in sol-gel spin coated titania films for annealing temperatures from 100 °C to 700 °C.

Original languageEnglish
Pages (from-to)5467-5470
Number of pages4
JournalThin Solid Films
Volume518
Issue number19
DOIs
Publication statusPublished - Jul 30 2010

Fingerprint

Sol-gels
gels
Annealing
broadband
Thin films
microstructure
Microstructure
annealing
titanium
Titanium
thin films
ellipsometry
Refractive index
refractivity
Decomposition
decomposition
Temperature
temperature
Spectroscopic ellipsometry
Gravimetric analysis

Keywords

  • Optical properties
  • Spectroscopic ellipsometry
  • Titanium dioxide

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Metals and Alloys
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Broad band optical characterization of sol-gel TiO2 thin film microstructure evolution with temperature. / Phadke, Sarika; Sorge, Judith D.; Hachtmann, Sherwood; Birnie, Dunbar P.

In: Thin Solid Films, Vol. 518, No. 19, 30.07.2010, p. 5467-5470.

Research output: Contribution to journalArticle

Phadke, Sarika ; Sorge, Judith D. ; Hachtmann, Sherwood ; Birnie, Dunbar P. / Broad band optical characterization of sol-gel TiO2 thin film microstructure evolution with temperature. In: Thin Solid Films. 2010 ; Vol. 518, No. 19. pp. 5467-5470.
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