Bulk defect chemistry and surface electronic behavior of Zn,Sn codoped In2O3 transparent conducting oxides

Steven P. Harvey; Thomas O. Mason; Christoph Körber; Andreas Klein

doi:10.1039/b822149a

Bulk defect chemistry and surface electronic behavior of Zn,Sn codoped In₂O₃ transparent conducting oxides

Steven P. Harvey, Thomas O. Mason, Christoph Körber, Andreas Klein

Northwestern University

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The electrical properties of the zinc and tin codoped indium oxide, In _(2-2x)Sn_xZn_xO₃ or ZITO, were investigated via high temperature electrical measurements over a range of pO₂. Results indicate the presence of the (2Sn_InO _i″)^x neutral defect cluster, which is also prevalent in indium-tin-oxide. Thin films of ZITO were deposited, annealed, and analyzed via photoelectron spectroscopy. Changes in the Fermi level position and core level binding energies were attributed to the neutral defect cluster affecting the free carrier content. An important correlation has been observed for the bixbyite structure transparent conducting oxides relating the crystal structure, the bulk defect chemistry, and the surface electronic properties.

Original language	English
Pages (from-to)	3099-3104
Number of pages	6
Journal	Physical Chemistry Chemical Physics
Volume	11
Issue number	17
DOIs	https://doi.org/10.1039/b822149a
Publication status	Published - Apr 24 2009

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ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Cite this

Harvey, S. P., Mason, T. O., Körber, C., & Klein, A. (2009). Bulk defect chemistry and surface electronic behavior of Zn,Sn codoped In₂O₃ transparent conducting oxides. Physical Chemistry Chemical Physics, 11(17), 3099-3104. https://doi.org/10.1039/b822149a

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10.1039/b822149a