C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state

Ofer Blum, Felix Frolow, David Milstein

Research output: Contribution to journal › Article

87 Citations (Scopus)

Abstract

Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

Original languageEnglish
Pages (from-to)258-259
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1991

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Iridium
Chemical activation
Oxidation
hexafluorobenzene

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state. / Blum, Ofer; Frolow, Felix; Milstein, David.

In: Journal of the Chemical Society, Chemical Communications, No. 4, 1991, p. 258-259.

Research output: Contribution to journal › Article

Blum, O, Frolow, F & Milstein, D 1991, 'C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 258-259. https://doi.org/10.1039/C39910000258
Blum O, Frolow F, Milstein D. C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state. Journal of the Chemical Society, Chemical Communications. 1991;(4):258-259. https://doi.org/10.1039/C39910000258
Blum, Ofer ; Frolow, Felix ; Milstein, David. / C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state. In: Journal of the Chemical Society, Chemical Communications. 1991 ; No. 4. pp. 258-259.
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