C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state

Ofer Blum; Felix Frolow; David Milstein

doi:10.1039/C39910000258

C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state

Ofer Blum, Felix Frolow, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Reaction of hexafluorobenzene with MeIr(PEt₃)₃ results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

Original language	English
Pages (from-to)	258-259
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39910000258
Publication status	Published - 1991

ASJC Scopus subject areas

Molecular Medicine

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title = "C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state",

abstract = "Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.",

author = "Ofer Blum and Felix Frolow and David Milstein",

year = "1991",

doi = "10.1039/C39910000258",

language = "English",

pages = "258--259",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "4",

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T1 - C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state

AU - Blum, Ofer

AU - Frolow, Felix

AU - Milstein, David

PY - 1991

Y1 - 1991

N2 - Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

AB - Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

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U2 - 10.1039/C39910000258

DO - 10.1039/C39910000258

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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