C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state

Ofer Blum, Felix Frolow, David Milstein

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

Original languageEnglish
Pages (from-to)258-259
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1991

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Iridium
Chemical activation
Oxidation
hexafluorobenzene

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "C-F bond activation by iridium(I). A unique process involving P-C bond cleavage, P-F bond formation and net retention of oxidation state",
abstract = "Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.",
author = "Ofer Blum and Felix Frolow and David Milstein",
year = "1991",
doi = "10.1039/C39910000258",
language = "English",
pages = "258--259",
journal = "Chemical Communications",
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AU - Frolow, Felix

AU - Milstein, David

PY - 1991

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AB - Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C-F bond cleavage, P-C bond cleavage and P-F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

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