Terminal alkynes, including those with acidic O-H groups, react with [Rh(PMe3)4]Cl in tetrahydrofuran (THF) or in water yielding cis-hydrido-σ-acetylide complexes via C-H activation; the molecular structure of cis-[Rh(PMe3)4(H)(C≡C-CH 2OH)]Cl has been determined by X-ray diffraction.
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - 1987|
ASJC Scopus subject areas
- Molecular Medicine