C-H rather than O-H activation: Synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

Todd B. Marder, David Zargarian, Joseph C. Calabrese, Thomas H. Herskovitz, David Milstein

Research output: Contribution to journalArticle

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Abstract

Terminal alkynes, including those with acidic O-H groups, react with [Rh(PMe3)4]Cl in tetrahydrofuran (THF) or in water yielding cis-hydrido-σ-acetylide complexes via C-H activation; the molecular structure of cis-[Rh(PMe3)4(H)(C≡C-CH 2OH)]Cl has been determined by X-ray diffraction.

Original languageEnglish
Pages (from-to)1484-1485
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
Publication statusPublished - 1987

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Rhodium
Alkynes
Molecular Structure
X-Ray Diffraction
Molecular structure
Chemical activation
X ray diffraction
Hydrogen
Water
tetrahydrofuran

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

C-H rather than O-H activation : Synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium. / Marder, Todd B.; Zargarian, David; Calabrese, Joseph C.; Herskovitz, Thomas H.; Milstein, David.

In: Journal of the Chemical Society, Chemical Communications, No. 19, 1987, p. 1484-1485.

Research output: Contribution to journalArticle

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