C-N bond hydrogenolysis of aniline and cyclohexylamine over TaO:X-Al2O3

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

TaOx grafted onto Al2O3 is investigated for C-N bond cleavage of amines under H2 pressure. Heteroaromatics such as aniline are stoichiometrically denitrogenated at high temperature, while cyclohexylamine is catalytically denitrogenated. UV-visible and X-ray photoelectron spectroscopy indicate the formation of a stable Ta-N species in the former case.

Original languageEnglish
Pages (from-to)6001-6004
Number of pages4
JournalNew Journal of Chemistry
Volume40
Issue number7
DOIs
Publication statusPublished - 2016

Fingerprint

Cyclohexylamines
Hydrogenolysis
Aniline
Amines
X ray photoelectron spectroscopy
Temperature
aniline

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Cite this

C-N bond hydrogenolysis of aniline and cyclohexylamine over TaO:X-Al2O3 . / Bachrach, Mark; Marks, Tobin J; Notestein, Justin M.

In: New Journal of Chemistry, Vol. 40, No. 7, 2016, p. 6001-6004.

Research output: Contribution to journalArticle

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