Cadmium-stabilized lead selenide nanocrystals for use in solar cells

Jeffrey M. Pietryga, Joanna L. Casson, Richard D. Schaller, Victor I. Klimov, Jennifer A. Hollingsworth

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Their unique optical properties have made semiconductor nanocrystals (NCs) the subject of intense research for use in solar cells. Even in the simplest scenario, in which semiconductor NCs are used as replacements for dyes in dye-sensitized cells, there is great potential for increased efficiency because of the broad-band, high-cross-section absorbance spectra, increased photostability and "carrier multiplication" (CM) demonstrated by semiconductor NCs. Lead selenide (PbSe) NCs are an especially promising candidate, because they possess near-to-mid infrared optical band gaps, and have demonstrated efficient CM. However, PbSe NCs are unstable under ambient conditions, undergoing band gap shifts and reduced surface quality that preclude their use in solar cells. Investigation of this instability has led to a method for stabilizing PbSe NCs with unique advantages to possible solar cell application. We will present the results of that study, along with a comparison study performed on the new cadmium-stabilized PbSe NCs.

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Publication statusPublished - 2007
Event234th ACS National Meeting - Boston, MA, United States
Duration: Aug 19 2007Aug 23 2007

Other

Other234th ACS National Meeting
CountryUnited States
CityBoston, MA
Period8/19/078/23/07

Fingerprint

Cadmium
Nanocrystals
Solar cells
Semiconductor materials
Coloring Agents
Optical band gaps
lead selenide
Surface properties
Energy gap
Optical properties
Infrared radiation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Pietryga, J. M., Casson, J. L., Schaller, R. D., Klimov, V. I., & Hollingsworth, J. A. (2007). Cadmium-stabilized lead selenide nanocrystals for use in solar cells. In ACS National Meeting Book of Abstracts

Cadmium-stabilized lead selenide nanocrystals for use in solar cells. / Pietryga, Jeffrey M.; Casson, Joanna L.; Schaller, Richard D.; Klimov, Victor I.; Hollingsworth, Jennifer A.

ACS National Meeting Book of Abstracts. 2007.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Pietryga, JM, Casson, JL, Schaller, RD, Klimov, VI & Hollingsworth, JA 2007, Cadmium-stabilized lead selenide nanocrystals for use in solar cells. in ACS National Meeting Book of Abstracts. 234th ACS National Meeting, Boston, MA, United States, 8/19/07.
Pietryga JM, Casson JL, Schaller RD, Klimov VI, Hollingsworth JA. Cadmium-stabilized lead selenide nanocrystals for use in solar cells. In ACS National Meeting Book of Abstracts. 2007
Pietryga, Jeffrey M. ; Casson, Joanna L. ; Schaller, Richard D. ; Klimov, Victor I. ; Hollingsworth, Jennifer A. / Cadmium-stabilized lead selenide nanocrystals for use in solar cells. ACS National Meeting Book of Abstracts. 2007.
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