Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

Alexander M. Spokoyny; Matthew G. Reuter; Charlotte L. Stern; Mark A. Ratner; Tamar Seideman; Chad A. Mirkin

doi:10.1021/ja902526k

Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

Alexander M. Spokoyny, Matthew G. Reuter, Charlotte L. Stern, Mark A. Ratner, Tamar Seideman, Chad A. Mirkin

Northwestern University

Research output: Contribution to journal › Article

93 Citations (Scopus)

Abstract

(Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

Original language	English
Pages (from-to)	9482-9483
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	27
DOIs	https://doi.org/10.1021/ja902526k
Publication status	Published - Jul 15 2009

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ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Cite this

Spokoyny, A. M., Reuter, M. G., Stern, C. L., Ratner, M. A., Seideman, T., & Mirkin, C. A. (2009). Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes. Journal of the American Chemical Society, 131(27), 9482-9483. https://doi.org/10.1021/ja902526k

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AU - Seideman, Tamar

AU - Mirkin, Chad A.

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AB - (Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

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10.1021/ja902526k