Carrier generation in multicomponent wide-bandgap oxides: InGaZnO 4

Altynbek Murat, Alexander U. Adler, Thomas O Mason, Julia E. Medvedeva

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

To exploit the full potential of multicomponent wide-bandgap oxides, an in-depth understanding of the complex defect chemistry and of the role played by the constituent oxides is required. In this work, thorough theoretical and experimental investigations are combined in order to explain the carrier generation and transport in crystalline InGaZnO4. Using first-principles density functional approach, we calculate the formation energies and transition levels of possible acceptor and donor point defects as well as the implied defect complexes in InGaZnO4 and determine the equilibrium defect and electron densities as a function of growth temperature and oxygen partial pressure. An excellent agreement of the theoretical results with our Brouwer analysis of the bulk electrical measurements for InGaZnO 4 establishes the Ga antisite defect, GaZn, as the major electron donor in InGaZnO4. Moreover, we show that the oxygen vacancies, long believed to be the carrier source in this oxide, are scarce. The proposed carrier generation mechanism also explains the observed intriguing behavior of the conductivity in In-rich vs Ga-rich InGaZnO4.

Original languageEnglish
Pages (from-to)5685-5692
Number of pages8
JournalJournal of the American Chemical Society
Volume135
Issue number15
DOIs
Publication statusPublished - Apr 17 2013

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Oxides
Energy gap
Defects
Electrons
Oxygen
Partial Pressure
Defect density
Growth temperature
Point defects
Oxygen vacancies
Partial pressure
Carrier concentration
Crystalline materials
Temperature
Growth

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Carrier generation in multicomponent wide-bandgap oxides : InGaZnO 4. / Murat, Altynbek; Adler, Alexander U.; Mason, Thomas O; Medvedeva, Julia E.

In: Journal of the American Chemical Society, Vol. 135, No. 15, 17.04.2013, p. 5685-5692.

Research output: Contribution to journalArticle

Murat, Altynbek ; Adler, Alexander U. ; Mason, Thomas O ; Medvedeva, Julia E. / Carrier generation in multicomponent wide-bandgap oxides : InGaZnO 4. In: Journal of the American Chemical Society. 2013 ; Vol. 135, No. 15. pp. 5685-5692.
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