Catalysing water oxidation using nature's metal

Gary W. Brudvig

doi:10.1038/s41929-017-0013-1

Catalysing water oxidation using nature's metal

Gary W. Brudvig

Yale University

Research output: Contribution to journal › Short survey › peer-review

5 Citations (Scopus)

Abstract

In nature, a manganese catalyst is used for photosynthetic water oxidation, but efforts to develop artificial manganese-based counterparts have been hampered by the lability of manganese complexes. By using a bulky and hydrophilic ligand, a water-soluble Mn₁₂ complex is found to be a stable and efficient water oxidation electrocatalyst.

Original language	English
Pages (from-to)	10-11
Number of pages	2
Journal	Nature Catalysis
Volume	1
Issue number	1
DOIs	https://doi.org/10.1038/s41929-017-0013-1
Publication status	Published - Jan 1 2018

ASJC Scopus subject areas

Catalysis
Bioengineering
Biochemistry
Process Chemistry and Technology

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AB - In nature, a manganese catalyst is used for photosynthetic water oxidation, but efforts to develop artificial manganese-based counterparts have been hampered by the lability of manganese complexes. By using a bulky and hydrophilic ligand, a water-soluble Mn12 complex is found to be a stable and efficient water oxidation electrocatalyst.

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Catalysing water oxidation using nature's metal

Abstract

ASJC Scopus subject areas

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