Abstract
Esters, amides, and peptides are important fine and bulk chemicals. Development of new green catalytic reactions for the synthesis of these products is highly desirable. Pincer complexes, particularly those that operate by "metal-ligand cooperation" involving aromatization-dearomatization of ligand motifs exhibit remarkable catalytic efficiency in the synthesis of these products from fundamental feedstocks such as alcohols, amines, and aminoalcohols. Gratifyingly, a range of useful products, including polyesters and polyamides, were efficiently prepared by the newly developed catalytic methods. These catalytic reactions proceed selectively under neutral, mild conditions, do not generate waste, and provide dihydrogen, which is valuable by itself.
| Original language | English |
|---|---|
| Title of host publication | Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis |
| Publisher | Wiley Blackwell |
| Pages | 1-30 |
| Number of pages | 30 |
| ISBN (Print) | 9783527681303, 9783527334421 |
| DOIs | |
| Publication status | Published - Aug 25 2014 |
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Keywords
- Amides
- Catalysis
- Esters
- Peptides
- Pincer complexes
- Ruthenium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Catalysis by Pincer Complexes : Synthesis of Esters, Amides, and Peptides. / Gunanathan, Chidambaram; Milstein, David.
Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis. Wiley Blackwell, 2014. p. 1-30.Research output: Chapter in Book/Report/Conference proceeding › Chapter
}
TY - CHAP
T1 - Catalysis by Pincer Complexes
T2 - Synthesis of Esters, Amides, and Peptides
AU - Gunanathan, Chidambaram
AU - Milstein, David
PY - 2014/8/25
Y1 - 2014/8/25
N2 - Esters, amides, and peptides are important fine and bulk chemicals. Development of new green catalytic reactions for the synthesis of these products is highly desirable. Pincer complexes, particularly those that operate by "metal-ligand cooperation" involving aromatization-dearomatization of ligand motifs exhibit remarkable catalytic efficiency in the synthesis of these products from fundamental feedstocks such as alcohols, amines, and aminoalcohols. Gratifyingly, a range of useful products, including polyesters and polyamides, were efficiently prepared by the newly developed catalytic methods. These catalytic reactions proceed selectively under neutral, mild conditions, do not generate waste, and provide dihydrogen, which is valuable by itself.
AB - Esters, amides, and peptides are important fine and bulk chemicals. Development of new green catalytic reactions for the synthesis of these products is highly desirable. Pincer complexes, particularly those that operate by "metal-ligand cooperation" involving aromatization-dearomatization of ligand motifs exhibit remarkable catalytic efficiency in the synthesis of these products from fundamental feedstocks such as alcohols, amines, and aminoalcohols. Gratifyingly, a range of useful products, including polyesters and polyamides, were efficiently prepared by the newly developed catalytic methods. These catalytic reactions proceed selectively under neutral, mild conditions, do not generate waste, and provide dihydrogen, which is valuable by itself.
KW - Amides
KW - Catalysis
KW - Esters
KW - Peptides
KW - Pincer complexes
KW - Ruthenium
UR - http://www.scopus.com/inward/record.url?scp=84922562297&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84922562297&partnerID=8YFLogxK
U2 - 10.1002/9783527681303.ch1
DO - 10.1002/9783527681303.ch1
M3 - Chapter
SN - 9783527681303
SN - 9783527334421
SP - 1
EP - 30
BT - Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis
PB - Wiley Blackwell
ER -