Abstract
DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).
| Original language | English |
|---|---|
| Title of host publication | ACS National Meeting Book of Abstracts |
| Volume | 230 |
| Publication status | Published - 2005 |
| Event | 230th ACS National Meeting - Washington, DC, United States Duration: Aug 28 2005 → Sep 1 2005 |
Other
| Other | 230th ACS National Meeting |
|---|---|
| Country | United States |
| City | Washington, DC |
| Period | 8/28/05 → 9/1/05 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Catalysis for hydrogen storage. / Linehan, John; Autrey, Tom; Fulton, John L.; Chen, Yongsheng; Balasubramanian, Mahalingam.
ACS National Meeting Book of Abstracts. Vol. 230 2005.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Catalysis for hydrogen storage
AU - Linehan, John
AU - Autrey, Tom
AU - Fulton, John L.
AU - Chen, Yongsheng
AU - Balasubramanian, Mahalingam
PY - 2005
Y1 - 2005
N2 - DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).
AB - DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).
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M3 - Conference contribution
VL - 230
BT - ACS National Meeting Book of Abstracts
ER -