Catalysis for hydrogen storage

John Linehan, Tom Autrey, John L. Fulton, Yongsheng Chen, Mahalingam Balasubramanian

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Volume230
Publication statusPublished - 2005
Event230th ACS National Meeting - Washington, DC, United States
Duration: Aug 28 2005Sep 1 2005

Other

Other230th ACS National Meeting
CountryUnited States
CityWashington, DC
Period8/28/059/1/05

Fingerprint

Hydrogen storage
Catalysis
X ray absorption fine structure spectroscopy
Boranes
Rhodium
Catalysts
Hydrogen fuels
Ruthenium
Hydrogen production
Fossil fuels
Ammonia
Nuclear magnetic resonance spectroscopy
Transition metals
Fuel cells
Hydrogen
Infrared spectroscopy
Kinetics
Substrates
Hot Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Linehan, J., Autrey, T., Fulton, J. L., Chen, Y., & Balasubramanian, M. (2005). Catalysis for hydrogen storage. In ACS National Meeting Book of Abstracts (Vol. 230)

Catalysis for hydrogen storage. / Linehan, John; Autrey, Tom; Fulton, John L.; Chen, Yongsheng; Balasubramanian, Mahalingam.

ACS National Meeting Book of Abstracts. Vol. 230 2005.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Linehan, J, Autrey, T, Fulton, JL, Chen, Y & Balasubramanian, M 2005, Catalysis for hydrogen storage. in ACS National Meeting Book of Abstracts. vol. 230, 230th ACS National Meeting, Washington, DC, United States, 8/28/05.
Linehan J, Autrey T, Fulton JL, Chen Y, Balasubramanian M. Catalysis for hydrogen storage. In ACS National Meeting Book of Abstracts. Vol. 230. 2005
Linehan, John ; Autrey, Tom ; Fulton, John L. ; Chen, Yongsheng ; Balasubramanian, Mahalingam. / Catalysis for hydrogen storage. ACS National Meeting Book of Abstracts. Vol. 230 2005.
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