Catalysis for hydrogen storage

John Linehan, Tom Autrey, John L. Fulton, Yongsheng Chen, Mahalingam Balasubramanian

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

A new aspect on the hydrogen release from NH 3BH 3 using a homogeneous ruthenium catalyst was presented. The boron NMR results of the ruthenium (Ru(DMSO) 4Cl 2) catalyzed reaction of NH 3BH 3 in methanol at room temperature showed that the boron cleanly and quickly converted from BH 3 attached to NH 3 to methylborate. During the catalysis, the Ru(DMSO) 4Cl 2 complex was completely converted to a new soluble catalytic species, which did not contain any Ru-S or Ru-Cl bonds. The metal-containing catalytic species (or its resting state) only had light element (O, B, or N) ligands directly bound to the ruthenium. The boron-containing reaction products were dependent upon the solvent and the reaction conditions. Efficient release of H 2 from NH 3BH 3 was shown. This is an abstract of a paper presented in the ACS Fuel Chemistry Meeting Fall 2005 (Washington, DC Fall 2005).

Original languageEnglish
Title of host publicationACS Division of Fuel Chemistry, Preprints
Pages540
Number of pages1
Volume50
Edition2
Publication statusPublished - 2005

Fingerprint

Hydrogen storage
Ruthenium
Catalysis
Boron
Reaction products
Methanol
Ligands
Nuclear magnetic resonance
Hydrogen
Catalysts
Metals
Temperature

ASJC Scopus subject areas

  • Energy(all)

Cite this

Linehan, J., Autrey, T., Fulton, J. L., Chen, Y., & Balasubramanian, M. (2005). Catalysis for hydrogen storage. In ACS Division of Fuel Chemistry, Preprints (2 ed., Vol. 50, pp. 540)

Catalysis for hydrogen storage. / Linehan, John; Autrey, Tom; Fulton, John L.; Chen, Yongsheng; Balasubramanian, Mahalingam.

ACS Division of Fuel Chemistry, Preprints. Vol. 50 2. ed. 2005. p. 540.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Linehan, J, Autrey, T, Fulton, JL, Chen, Y & Balasubramanian, M 2005, Catalysis for hydrogen storage. in ACS Division of Fuel Chemistry, Preprints. 2 edn, vol. 50, pp. 540.
Linehan J, Autrey T, Fulton JL, Chen Y, Balasubramanian M. Catalysis for hydrogen storage. In ACS Division of Fuel Chemistry, Preprints. 2 ed. Vol. 50. 2005. p. 540
Linehan, John ; Autrey, Tom ; Fulton, John L. ; Chen, Yongsheng ; Balasubramanian, Mahalingam. / Catalysis for hydrogen storage. ACS Division of Fuel Chemistry, Preprints. Vol. 50 2. ed. 2005. pp. 540
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