Abstract
Spectroscopy of catalyst systems under actual operating conditions, or operando spectroscopy, has become instrumental in helping to determine the structures and mechanisms of catalytic systems. Operando spectroscopy is differentiated from in situ spectroscopy in that operando spectroscopy occurs under the actual catalyst operating conditions. In addition, a measure of the catalyst activity is also critical during operando spectroscopy. Operando spectroscopy has revealed that some catalytic systems operate under much different conditions than previously believed based on ex situ analysis. We present some of our recent work using operando XAFS of catalytic systems varying from hydrogen release of hydrogen storage materials to benzene hydrogenation. We present a basic introduction into XAFS and its use as an operando technique and show how this technique can be used to differentiate between catalyst containing highly dispersed nanoparticles and organometallic clusters.
| Original language | English |
|---|---|
| Title of host publication | ACS National Meeting Book of Abstracts |
| Publication status | Published - 2009 |
| Event | 237th National Meeting and Exposition of the American Chemical Society, ACS 2009 - Salt Lake City, UT, United States Duration: Mar 22 2009 → Mar 26 2009 |
Other
| Other | 237th National Meeting and Exposition of the American Chemical Society, ACS 2009 |
|---|---|
| Country | United States |
| City | Salt Lake City, UT |
| Period | 3/22/09 → 3/26/09 |
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ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
Cite this
Catalyst structure determination using operando XAFS. / Linehan, John; Fulton, John L.; Balasubramanian, Mahalingam; Chen, Yongsheng; Autrey, Tom; Szymczak, Nathaniel K.; Franz, James A.; Finke, Richard G.; Bitterwolf, Thomas E.; Shaw, Wendy J.; Smurthwaite, Tricia.
ACS National Meeting Book of Abstracts. 2009.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Catalyst structure determination using operando XAFS
AU - Linehan, John
AU - Fulton, John L.
AU - Balasubramanian, Mahalingam
AU - Chen, Yongsheng
AU - Autrey, Tom
AU - Szymczak, Nathaniel K.
AU - Franz, James A.
AU - Finke, Richard G.
AU - Bitterwolf, Thomas E.
AU - Shaw, Wendy J.
AU - Smurthwaite, Tricia
PY - 2009
Y1 - 2009
N2 - Spectroscopy of catalyst systems under actual operating conditions, or operando spectroscopy, has become instrumental in helping to determine the structures and mechanisms of catalytic systems. Operando spectroscopy is differentiated from in situ spectroscopy in that operando spectroscopy occurs under the actual catalyst operating conditions. In addition, a measure of the catalyst activity is also critical during operando spectroscopy. Operando spectroscopy has revealed that some catalytic systems operate under much different conditions than previously believed based on ex situ analysis. We present some of our recent work using operando XAFS of catalytic systems varying from hydrogen release of hydrogen storage materials to benzene hydrogenation. We present a basic introduction into XAFS and its use as an operando technique and show how this technique can be used to differentiate between catalyst containing highly dispersed nanoparticles and organometallic clusters.
AB - Spectroscopy of catalyst systems under actual operating conditions, or operando spectroscopy, has become instrumental in helping to determine the structures and mechanisms of catalytic systems. Operando spectroscopy is differentiated from in situ spectroscopy in that operando spectroscopy occurs under the actual catalyst operating conditions. In addition, a measure of the catalyst activity is also critical during operando spectroscopy. Operando spectroscopy has revealed that some catalytic systems operate under much different conditions than previously believed based on ex situ analysis. We present some of our recent work using operando XAFS of catalytic systems varying from hydrogen release of hydrogen storage materials to benzene hydrogenation. We present a basic introduction into XAFS and its use as an operando technique and show how this technique can be used to differentiate between catalyst containing highly dispersed nanoparticles and organometallic clusters.
UR - http://www.scopus.com/inward/record.url?scp=78649497613&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78649497613&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:78649497613
SN - 9780841224414
BT - ACS National Meeting Book of Abstracts
ER -