Catalytic activation of carbon-fluorine bonds by a soluble transition metal complex

Michael Aizenberg, David Milstein

Research output: Contribution to journalArticle

259 Citations (Scopus)

Abstract

Homogeneous catalytic activation of the strong carbon-fluorine bonds under mild conditions was achieved with the use of rhodium complexes as catalysts. The catalytic reactions between polyfluorobenzenes and hydrosilanes result in substitution of fluorine atoms by hydrogen atoms and are chemo- and regioselective. With individual stoichiometric steps observed and combined, and with intermediates isolated and fully characterized (including crystal structures), these systems demonstrate the effectiveness of a rational approach to catalytic design.

Original languageEnglish
Pages (from-to)359-361
Number of pages3
JournalScience
Volume265
Issue number5170
Publication statusPublished - Jul 15 1994

ASJC Scopus subject areas

  • General

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