Catalytic Applications of Vanadium

A Mechanistic Perspective

Ryan R. Langeslay, David M. Kaphan, Christopher L. Marshall, Peter C Stair, Alfred P. Sattelberger, Massimiliano Delferro

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Original languageEnglish
JournalChemical Reviews
DOIs
Publication statusAccepted/In press - Jan 1 2018

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Vanadium
Carbon
Alkanes
Ring opening polymerization
Alkenes
Dehydrogenation
Ketones
Sulfur
Aldehydes
Catalysis
Hydrogenation
Alcohols
Oxidation
Kinetics

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Langeslay, R. R., Kaphan, D. M., Marshall, C. L., Stair, P. C., Sattelberger, A. P., & Delferro, M. (Accepted/In press). Catalytic Applications of Vanadium: A Mechanistic Perspective. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.8b00245

Catalytic Applications of Vanadium : A Mechanistic Perspective. / Langeslay, Ryan R.; Kaphan, David M.; Marshall, Christopher L.; Stair, Peter C; Sattelberger, Alfred P.; Delferro, Massimiliano.

In: Chemical Reviews, 01.01.2018.

Research output: Contribution to journalArticle

Langeslay, Ryan R. ; Kaphan, David M. ; Marshall, Christopher L. ; Stair, Peter C ; Sattelberger, Alfred P. ; Delferro, Massimiliano. / Catalytic Applications of Vanadium : A Mechanistic Perspective. In: Chemical Reviews. 2018.
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